1,1'-(4,6-bis(hexyloxy)-1,3-phenylene)bis(4-(5-bromo-2,4-bis(hexyloxy)phenyl)-1H-1,2,3-triazole)

Base Information

Chemical Name:1,1'-(4,6-bis(hexyloxy)-1,3-phenylene)bis(4-(5-bromo-2,4-bis(hexyloxy)phenyl)-1H-1,2,3-triazole)
CAS No.:1276582-15-0
Molecular Formula:C₅₈H₈₆Br₂N₆O₆
Molecular Weight:1123.17
Hs Code.:

Synonyms:

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Chemical Property of 1,1'-(4,6-bis(hexyloxy)-1,3-phenylene)bis(4-(5-bromo-2,4-bis(hexyloxy)phenyl)-1H-1,2,3-triazole)

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Technology Process of 1,1'-(4,6-bis(hexyloxy)-1,3-phenylene)bis(4-(5-bromo-2,4-bis(hexyloxy)phenyl)-1H-1,2,3-triazole)

There total 11 articles about 1,1'-(4,6-bis(hexyloxy)-1,3-phenylene)bis(4-(5-bromo-2,4-bis(hexyloxy)phenyl)-1H-1,2,3-triazole) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 1276582-04-7
1-bromo-5-ethynyl-2,4-bis(hexyloxy)benzene

: 1276581-77-1
1,5-diazido-2,4-bis(hexyloxy)benzene

: 1276582-15-0
1,1'-(4,6-bis(hexyloxy)-1,3-phenylene)bis(4-(5-bromo-2,4-bis(hexyloxy)phenyl)-1H-1,2,3-triazole)

Guidance literature:: With copper(ll) sulfate pentahydrate; sodium L-ascorbate; tris[(1-benzyl-1H-1,2,3-triazol-4yl)methyl]amine; In dichloromethane; water; tert-butyl alcohol; for 0.5h; Inert atmosphere;
DOI:10.1002/chem.201002491

Reference yield:

: 108-46-3
recorcinol

: 1276582-15-0
1,1'-(4,6-bis(hexyloxy)-1,3-phenylene)bis(4-(5-bromo-2,4-bis(hexyloxy)phenyl)-1H-1,2,3-triazole)

Guidance literature:: Multi-step reaction with 5 steps

1: 18-crown-6 ether; tetra-(n-butyl)ammonium iodide; potassium carbonate / acetonitrile / 20 °C / Inert atmosphere; Reflux

2: benzyltrimethylazanium tribroman-2-uide / methanol; dichloromethane

3: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride / tetrahydrofuran / 80 °C / Inert atmosphere

4: potassium hydroxide / toluene / 2 h / 90 °C

5: copper(ll) sulfate pentahydrate; sodium L-ascorbate; tris[(1-benzyl-1H-1,2,3-triazol-4yl)methyl]amine / dichloromethane; water; tert-butyl alcohol / 0.5 h / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; copper(ll) sulfate pentahydrate; 18-crown-6 ether; tetra-(n-butyl)ammonium iodide; potassium carbonate; sodium L-ascorbate; benzyltrimethylazanium tribroman-2-uide; potassium hydroxide; tris[(1-benzyl-1H-1,2,3-triazol-4yl)methyl]amine; In tetrahydrofuran; methanol; dichloromethane; water; toluene; acetonitrile; tert-butyl alcohol;
DOI:10.1002/chem.201002491

Reference yield:

: 1,5-dibromo-2,4-bis(hexyloxy)benzene

: 1276582-15-0
1,1'-(4,6-bis(hexyloxy)-1,3-phenylene)bis(4-(5-bromo-2,4-bis(hexyloxy)phenyl)-1H-1,2,3-triazole)

Guidance literature:: Multi-step reaction with 3 steps

1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride / tetrahydrofuran / 80 °C / Inert atmosphere

2: potassium hydroxide / toluene / 2 h / 90 °C

3: copper(ll) sulfate pentahydrate; sodium L-ascorbate; tris[(1-benzyl-1H-1,2,3-triazol-4yl)methyl]amine / dichloromethane; water; tert-butyl alcohol / 0.5 h / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; copper(ll) sulfate pentahydrate; sodium L-ascorbate; potassium hydroxide; tris[(1-benzyl-1H-1,2,3-triazol-4yl)methyl]amine; In tetrahydrofuran; dichloromethane; water; toluene; tert-butyl alcohol;
DOI:10.1002/chem.201002491