Ph₃AsAlI₃

Base Information

• Chemical Name: Ph₃AsAlI₃
• CAS No.: 1237071-39-4
• Molecular Formula: C₁₈H₁₅AlAsI₃
• Molecular Weight: 713.934
• Mol file: 1237071-39-4.mol

Synonyms:

Chemical Property of Ph₃AsAlI₃

Chemical Property:

Purity/Quality:

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Technology Process of Ph₃AsAlI₃

There total 2 articles about Ph₃AsAlI₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

triphenyl-arsane (603-32-7) + aluminium(III) iodide (7784-23-8) → Ph3AsAlI3 (1237071-39-4)

Guidance literature:

In CH₂Cl₂; (N2, glovebox); addn. of CH2Cl2 soln. of arsine deriv. to CH2Cl2 soln. of aluminium compd., stirring for 30 min; layering with hexane, keeping overnight at -25°C, isolation of ppt., washing with ether, IR and NMR;

DOI:10.1139/V10-029

Reference yield:

aluminium(III) iodide + triphenyl-arsane (603-32-7) → Ph3AsAlI3 (1237071-39-4)

Guidance literature:

In toluene; for 0.75h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c4dt02051k

upstream raw materials:

triphenyl-arsane

aluminium(III) iodide