[((CH₃)5C₅)Ru(NCCH₃)2(P(C₃H₇)2NHC₆H₅)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[((CH₃)5C₅)Ru(NCCH₃)2(P(C₃H₇)2NHC₆H₅)]B(C₆H₅)4

Base Information

• Chemical Name: [((CH₃)5C₅)Ru(NCCH₃)2(P(C₃H₇)2NHC₆H₅)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[((CH₃)5C₅)Ru(NCCH₃)2(P(C₃H₇)2NHC₆H₅)]B(C₆H₅)4
• CAS No.: 886210-53-3
• Molecular Formula: C₂₄H₂₀B*C₂₆H₄₁N₃PRu
• Molecular Weight: 846.909
• Mol file: 886210-53-3.mol

Synonyms:

Chemical Property of [((CH₃)5C₅)Ru(NCCH₃)2(P(C₃H₇)2NHC₆H₅)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[((CH₃)5C₅)Ru(NCCH₃)2(P(C₃H₇)2NHC₆H₅)]B(C₆H₅)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [((CH₃)5C₅)Ru(NCCH₃)2(P(C₃H₇)2NHC₆H₅)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[((CH₃)5C₅)Ru(NCCH₃)2(P(C₃H₇)2NHC₆H₅)]B(C₆H₅)4

There total 1 articles about [((CH₃)5C₅)Ru(NCCH₃)2(P(C₃H₇)2NHC₆H₅)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[((CH₃)5C₅)Ru(NCCH₃)2(P(C₃H₇)2NHC₆H₅)]B(C₆H₅)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate + sodium tetraphenyl borate (143-66-8) + P(C3H7)2NHC6H5 (70589-60-5) → [((CH3)5C5)Ru(NCCH3)2(P(C3H7)2NHC6H5)](1+)*B(C6H5)4(1-)=[((CH3)5C5)Ru(NCCH3)2(P(C3H7)2NHC6H5)]B(C6H5)4 (886210-53-3)

Guidance literature:

In methanol; dichloromethane; under N2 or Ar, Schlenk setup; stoich. mixt. stirred at room temp. for 1h, evapd., dissolved in MeOH, excess NaBPh4 added; filtered off, washed (EtOH, petroleum ether), dried (vac.); elem. anal.;

DOI:10.1002/ejic.200500034

Reference yield: 55.0%

hepta-1,6-diyne (2396-63-6) + [((CH3)5C5)Ru(NCCH3)2(P(C3H7)2NHC6H5)](1+)*B(C6H5)4(1-)=[((CH3)5C5)Ru(NCCH3)2(P(C3H7)2NHC6H5)]B(C6H5)4 (886210-53-3) → [((CH3)5C5)Ru(η4-C4H3(CH2)3)(P(C3H7)2N(C6H5)-κ1N)]B(C6H5)4

Guidance literature:

In dichloromethane; under N2 or Ar, Schlenk setup; slight excess of ligand (0.55 mmol) addedto metal compd. (0.5 mmol), mixt. stirred at room temp. for 1 h, evapd.; washed (Et2O, petroleum ether), dried (vac.); recrystd. (acetone, petroleum ether), elem. anal.;

DOI:10.1002/ejic.200500034

Reference yield: 53.0%

[((CH3)5C5)Ru(NCCH3)2(P(C3H7)2NHC6H5)](1+)*B(C6H5)4(1-)=[((CH3)5C5)Ru(NCCH3)2(P(C3H7)2NHC6H5)]B(C6H5)4 (886210-53-3) + trimethylsilylacetylene (1066-54-2) → [((CH3)5C5)Ru(CH3CN)(η2-(CH3)3SiCHCH(C6H4)NHP(C3H7)2-κ1P)]B(C6H5)4 (886210-57-7)

Guidance literature:

In 1,2-dichloro-ethane; under N2 or Ar, Schlenk setup; ligand (0.57 mmol) added to metal compd. (0.5 mmol), mixt. stirred 5 min at 60°C and at room temp. for 1 h, evapd.; washed (Et2O, petroleum ether), dried (vac.); recrystd. (acetone, petroleum ether), elem. anal.;

DOI:10.1002/ejic.200500034

upstream raw materials:

sodium tetraphenyl borate

P(C₃H₇)2NHC₆H₅

Downstream raw materials:

[((CH3)5C5)Ru(CH3CN)(η2-C4H9CHCH(C6H4)NHP(C3H7)2-κ1P)]B(C6H5)4*(CH3)2CO

[((CH3)5C5)Ru(CH3CN)(η2-(CH3)3SiCHCH(C6H4)NHP(C3H7)2-κ1P)]B(C6H5)4