9⁽¹⁰⁾-epoxy-10,12(Z),15(Z)-octadecatrienoic acid

Base Information

• Chemical Name: 9⁽¹⁰⁾-epoxy-10,12(Z),15(Z)-octadecatrienoic acid
• CAS No.: 868281-09-8
• Molecular Formula: C₁₈H₃₀O₃
• Molecular Weight: 294.434

Synonyms:

Chemical Property of 9⁽¹⁰⁾-epoxy-10,12(Z),15(Z)-octadecatrienoic acid

Chemical Property:

Purity/Quality:

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Technology Process of 9⁽¹⁰⁾-epoxy-10,12(Z),15(Z)-octadecatrienoic acid

There total 3 articles about 9⁽¹⁰⁾-epoxy-10,12(Z),15(Z)-octadecatrienoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(9Z,12Z,15Z)-octadeca-9-12,15-trienoic acid (463-40-1,1955-33-5,21661-10-9,21661-09-6,21661-13-2,21661-11-0) → 12,13-Epoxylinolenic acid (349112-29-4,100019-37-2,88159-18-6) + 9(10)-epoxy-10,12(Z),15(Z)-octadecatrienoic acid (868281-09-8,36747-82-7) + 15,16-cis-epoxy-octadeca-9Z,12Z-dienoic acid (64044-08-2)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 0.5h;

DOI:10.1007/s11745-017-4271-0

Reference yield:

(9Z,12Z,15Z)-octadeca-9-12,15-trienoic acid (463-40-1,1955-33-5,21661-10-9,21661-09-6,21661-13-2,21661-11-0) → 12,13-Epoxylinolenic acid (349112-29-4,100019-37-2,88159-18-6) + 15-16-monoepoxyoctadeca-9,12-dieneoic acid (710296-22-3,64044-08-2) + 9(10)-epoxy-10,12(Z),15(Z)-octadecatrienoic acid (868281-09-8,36747-82-7)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid;

DOI:10.1246/cl.1984.409

Reference yield:

(9Z,12Z,15Z)-octadeca-9-12,15-trienoic acid (463-40-1,1955-33-5,21661-10-9,21661-09-6,21661-13-2,21661-11-0) → (10E,12Z,15Z)-9-hydroperoxy-10,12,15-octadecatrienoic acid (64265-94-7) + 9(10)-epoxy-10,12(Z),15(Z)-octadecatrienoic acid (868281-09-8,36747-82-7)

Guidance literature:

With recombinant Colletotrichum graminicola 9S-fatty acid dioxygenase-allene oxide synthase; In aq. buffer; pH=7.6; Cooling with ice; Enzymatic reaction;

DOI:10.1016/j.bbalip.2015.11.009

upstream raw materials:

(9Z,12Z,15Z)-octadeca-9-12,15-trienoic acid

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