μ-[2,2-diphenylhydrazido(2-)-N(1)(Ti(1,2)),N(2)(Ti(1))]-[μ-2,2-diphenylhydrazido(2-)-N(1)]-bis[chloro(η-cyclopentadienyl)titanium(IV)]

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Chemical Name:μ-[2,2-diphenylhydrazido(2-)-N(1)(Ti(1,2)),N(2)(Ti(1))]-[μ-2,2-diphenylhydrazido(2-)-N(1)]-bis[chloro(η-cyclopentadienyl)titanium(IV)]
CAS No.:103432-50-4
Molecular Formula:C₃₄H₃₀Cl₂N₄Ti₂
Molecular Weight:661.305
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Chemical Property of μ-[2,2-diphenylhydrazido(2-)-N(1)(Ti(1,2)),N(2)(Ti(1))]-[μ-2,2-diphenylhydrazido(2-)-N(1)]-bis[chloro(η-cyclopentadienyl)titanium(IV)]

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Technology Process of μ-[2,2-diphenylhydrazido(2-)-N(1)(Ti(1,2)),N(2)(Ti(1))]-[μ-2,2-diphenylhydrazido(2-)-N(1)]-bis[chloro(η-cyclopentadienyl)titanium(IV)]

There total 3 articles about μ-[2,2-diphenylhydrazido(2-)-N(1)(Ti(1,2)),N(2)(Ti(1))]-[μ-2,2-diphenylhydrazido(2-)-N(1)]-bis[chloro(η-cyclopentadienyl)titanium(IV)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 1270-98-0
cyclopentadienyl titanium(IV) trichloride

: 530-47-2,29666-92-0
N,N-diphenylhydrazine hydrochloride

: 103432-50-4
μ-[2,2-diphenylhydrazido(2-)-N(1)(Ti(1,2)),N(2)(Ti(1))]-[μ-2,2-diphenylhydrazido(2-)-N(1)]-bis[chloro(η-cyclopentadienyl)titanium(IV)]

Guidance literature:: With n-butyl lithium; In hexane; toluene; byproducts: LiCl; a soln. of n-butyl lithium in hexane added to a suspn. of diphenylhydrazinium chloride; heated for 1 h; Ti-complex and a soln. of n-butyl lithium in hexane added; heated at 80°c for 0.5 h; filtered; extracted with toluene; evapd.; dissolved in CH2Cl2 and hexane; filtered; dried in vacuo; recrystd. from toluene/hexane at 20°C; elem. anal.;
DOI:10.1039/DT9860000393

Reference yield: 36.0%

: 188477-99-8
(η-C5H5)TiCl(NBu(t))(C5H5N)

: 530-50-7
1,1-Diphenylhydrazine

: 103432-50-4
μ-[2,2-diphenylhydrazido(2-)-N(1)(Ti(1,2)),N(2)(Ti(1))]-[μ-2,2-diphenylhydrazido(2-)-N(1)]-bis[chloro(η-cyclopentadienyl)titanium(IV)]

Guidance literature:: In benzene; byproducts: (t-Bu)NH2; (Ar or N2); using Schlenk techniques; addn. of soln. of Ph2NNH2 in benzene to stirred soln. of (C5H5)Ti(N(t-Bu))Cl(py) in benzene, stirring for 16 h; removal of volatiles under reduced pressure, washing with pentane, drying under reduced pressure;
DOI:10.1021/om200068k