Technology Process of 1L-1,4,6-tri-O-benzoyl-chiro-inositol 2,3,5-tris(diethyl phosphate)
There total 7 articles about 1L-1,4,6-tri-O-benzoyl-chiro-inositol 2,3,5-tris(diethyl phosphate) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1: pyridine / 2 h / Ambient temperature
2: 94 percent / H2 / 5percent Pd/C / ethanol / 12 h / Ambient temperature
3: 1) N,N-diisopropylethylamine, 2) 70percent aq. t-BuOOH / 1a) acetonitrile, -4 deg C, 30 min, 1b) up to room temp., 2 h, 2) room temp., overnight
With
pyridine; tert.-butylhydroperoxide; hydrogen; N-ethyl-N,N-diisopropylamine;
palladium on activated charcoal;
In
ethanol;
DOI:10.1016/0008-6215(92)85042-X
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 94 percent / H2 / 5percent Pd/C / ethanol / 12 h / Ambient temperature
2: 1) N,N-diisopropylethylamine, 2) 70percent aq. t-BuOOH / 1a) acetonitrile, -4 deg C, 30 min, 1b) up to room temp., 2 h, 2) room temp., overnight
With
tert.-butylhydroperoxide; hydrogen; N-ethyl-N,N-diisopropylamine;
palladium on activated charcoal;
In
ethanol;
DOI:10.1016/0008-6215(92)85042-X
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1) Bu2SnO, Bu4NI / 1) MeCN, reflux, 15 h, 2) reflux, 24 h
2: pyridine / 2 h / Ambient temperature
3: 94 percent / H2 / 5percent Pd/C / ethanol / 12 h / Ambient temperature
4: 1) N,N-diisopropylethylamine, 2) 70percent aq. t-BuOOH / 1a) acetonitrile, -4 deg C, 30 min, 1b) up to room temp., 2 h, 2) room temp., overnight
With
pyridine; tert.-butylhydroperoxide; hydrogen; tetra-(n-butyl)ammonium iodide; di(n-butyl)tin oxide; N-ethyl-N,N-diisopropylamine;
palladium on activated charcoal;
In
ethanol;
DOI:10.1016/0008-6215(92)85042-X
