(η6-mesitylene)[η5-((diphenylphosphino)methyl)cyclopentadienyl]iron(II) hexafluorophosphate

Base Information

Chemical Name:(η6-mesitylene)[η5-((diphenylphosphino)methyl)cyclopentadienyl]iron(II) hexafluorophosphate
CAS No.:366011-06-5
Molecular Formula:C₂₇H₂₈FeP*F₆P
Molecular Weight:584.304
Hs Code.:

Synonyms:

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Chemical Property of (η6-mesitylene)[η5-((diphenylphosphino)methyl)cyclopentadienyl]iron(II) hexafluorophosphate

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Technology Process of (η6-mesitylene)[η5-((diphenylphosphino)methyl)cyclopentadienyl]iron(II) hexafluorophosphate

There total 1 articles about (η6-mesitylene)[η5-((diphenylphosphino)methyl)cyclopentadienyl]iron(II) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: ammonium hexafluorophosphate

: ((diphenylphosphino)methyl)ferrocene

: 108-67-8
1,3,5-trimethyl-benzene

: (1,3,5-trimethyl-η6-benzene)(η5-cyclopentadienyl)iron(II) hexafluorophosphate

: 366011-06-5
(η6-mesitylene)[η5-((diphenylphosphino)methyl)cyclopentadienyl]iron(II) hexafluorophosphate

Guidance literature:: With aluminium trichloride; water; aluminium; In cyclohexane; AlCl3, Al, ferrocene derivative, 1,3,5-mesitylene, and water were refluxed in cyclohexane for 5 h, mixt. was cooled to 0°C, water was addd, aq. layer was separated, NH4PF6 was added; ppt. was filtered, washed with cold water, dried and recrystd. from CH2Cl2/water;
DOI:10.1021/om010440e

Reference yield: 31.0%

: 1-phenyl-2,5-bis((-)-menthyl)phosphole

: 366011-06-5
(η6-mesitylene)[η5-((diphenylphosphino)methyl)cyclopentadienyl]iron(II) hexafluorophosphate

: 1'-((diphenylphosphino)methyl)-2,5-bis[(-)-menthyl]-1-phosphaferrocene

Guidance literature:: With lithium; In 1,4-dioxane; Li was added to soln. phosphole in THF at room temp. and stirred, solvent was removed in vacuo, residue was dissolved in 1,4-dioxane and added to soln. ferrocene derivative in 1,4-dioxane at 100°C and stirred for 2 h at this temp.; mixt. was cooled, benzene was added, soln. was filtered and evapd. to dryness, residue was chromed. on silica (hexane/benzene 4:1) under N2; elem. anal.;
DOI:10.1021/om010440e

Reference yield: 10.0%

: 366011-06-5
(η6-mesitylene)[η5-((diphenylphosphino)methyl)cyclopentadienyl]iron(II) hexafluorophosphate

: 448901-38-0
1-phenyl-2,5-dicyclohexylphosphole

: 803740-05-8
1'-(diphenylphosphinomethyl)-2,5-dicyclohexyl-1-phosphaferrocene

Guidance literature:: With Li; In 1,4-dioxane; (N2 or Ar); using Schlenk techniques; addn. of Li to soln. of 2,5-dicyclohexyl-1-phenylphosphole in dioxane at room temp.; stirring at 40°C; addn. to soln. of (PPh2CH2C5H4)Fe(C6H3Me3) in 1,4-dioxane at 100°C; stirring for 2 h at this temp.; cooling, addn. of benzene; filtration through Celite, evapn. to dryness under reduced pressure, chromy. on silica gel twice (first elution with hexane/toluene =4/1, second elution with hexane/CH2Cl2 = 10/1) under N2;elem. anal.;
DOI:10.1016/j.ica.2004.05.019