[(trans-PdBr(PMe2Ph)2)2(μ2-C6(CHO)3Br)]

Base Information

• Chemical Name: [(trans-PdBr(PMe2Ph)2)2(μ2-C6(CHO)3Br)]
• CAS No.: 1192614-44-0
• Molecular Formula: C₄₁H₄₇Br₃O₃P₄Pd₂
• Molecular Weight: 1164.27
• Mol file: 1192614-44-0.mol

Synonyms:

Chemical Property of [(trans-PdBr(PMe2Ph)2)2(μ2-C6(CHO)3Br)]

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of [(trans-PdBr(PMe2Ph)2)2(μ2-C6(CHO)3Br)]

There total 1 articles about [(trans-PdBr(PMe2Ph)2)2(μ2-C6(CHO)3Br)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

Dimethyl(phenyl)phosphine (672-66-2) + 2,4,6-tribromo-1,3,5-benzenetricarboxaldehyde (191529-09-6) + bis(dibenzylideneacetone)-palladium(0) (32005-36-0) → [(trans-PdBr(PMe2Ph)2)2(μ2-C6(CHO)3Br)] (1192614-44-0)

Guidance literature:

In toluene; under N2; Pd(dba)2 (0.25 mmol) and C6(CHO)3Br3 (0.125 mmol) were stirredfor 2-3 min in toluene at room temp.; then PMe2Ph (0.5 mmol) was added; stirring for 2 h under the same conditions; solvent was evapd. to dryness, residue was extd. with CH2Cl2; ext. was filtered, concd.; Et2O was added to ppt. solid; it was filtered off, washed with Et2O; TLC on silica gel (acetone/n-hexane (4:1) as eluent); recrystn. from CH2Cl2/Et2O; elem. anal.;

DOI:10.1021/om9005966

upstream raw materials:

Dimethyl(phenyl)phosphine

2,4,6-tribromo-1,3,5-benzenetricarboxaldehyde

bis(dibenzylideneacetone)-palladium⁽⁰⁾