[(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-t-Bu)

Base Information

Chemical Name:[(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-t-Bu)
CAS No.:691888-01-4
Molecular Formula:C₄₀H₆₆N₃Sc
Molecular Weight:633.94
Hs Code.:

Synonyms:

Suppliers and Price of [(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-t-Bu)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-t-Bu)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-t-Bu)

There total 2 articles about [(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-t-Bu) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 691887-99-7
[(((CH₃)2CH)2C₆H₃NC(C(CH₃)3)CHC(C(CH₃)3)NC₆H₃(CH(CH₃)2)2)ScCl(NHC(CH₃)3)]

: 917-54-4
methyllithium

: 691888-01-4
[(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-t-Bu)

Guidance literature:: In toluene; byproducts: LiCl; (Ar); Schlenk technique; toluene was condensed into Sc complex and MeLi;mixt. was stirred at 35°C overnight; solvent removed (vac.); hexane added; mixt. warmed to 40°C; filtered; extd. (hexane); solvent removed (vac.); recrystd. (hexane, -36°C); elem. anal.;
DOI:10.1021/om034345c

Reference yield:

: 241165-09-3
[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

: 691888-01-4
[(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-t-Bu)

Guidance literature:: Multi-step reaction with 2 steps

1: toluene

2: toluene

In toluene;
DOI:10.1021/om034345c

Reference yield: 97.0%

: 691888-01-4
[(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-t-Bu)

: 1109-15-5
tris(pentafluorophenyl)borate

: (((CH₃)2CH)2C₆H₃NC(C(CH₃)3)CHC(C(CH₃)3)NC₆H₃(CH(CH₃)2)2)Sc(NHC(CH₃)3)(CH₃B(C₆F₅)3)

Guidance literature:: In hexane; soln. B(C6F5)3 in hexane was added dropwise to soln. Sc complex in hexane, stirred for 2 h at room temp. and left overnight at -36°C; ppt. was dried in vacuo; elem. anal.;
DOI:10.1021/om060197p