Silane, [(1,3-diphenyl-1-propenyl)oxy]trimethyl-, (E)-

Base Information

• Chemical Name: Silane, [(1,3-diphenyl-1-propenyl)oxy]trimethyl-, (E)-
• CAS No.: 105762-50-3
• Molecular Formula: C18H22OSi
• Molecular Weight: 282.458
• Mol file: 105762-50-3.mol

Synonyms:

Chemical Property of Silane, [(1,3-diphenyl-1-propenyl)oxy]trimethyl-, (E)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silane, [(1,3-diphenyl-1-propenyl)oxy]trimethyl-, (E)-

There total 5 articles about Silane, [(1,3-diphenyl-1-propenyl)oxy]trimethyl-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trimethyl<2-(phenylthio)-3-phenylpropanoyl>silane (66132-89-6) + phenyllithium (591-51-5) → (Z)-((1,3-diphenylprop-1-en-1-yl)oxy)trimethylsilane (105762-60-5) + (E)-1,3-diphenyl-1-(trimethylsiloxy)-1-propene (105762-50-3)

Guidance literature:

In diethyl ether; Yield given. Yields of byproduct given. Title compound not separated from byproducts; 1.) -78 deg C, 10 min, 2.) from -78 to 0 deg C, 30 min;

DOI:10.1021/ja00170a026

Reference yield:

1,3-Diphenyl-2-phenylsulfanyl-1-trimethylsilanyl-propan-1-ol (105762-74-1,105762-75-2) → (Z)-((1,3-diphenylprop-1-en-1-yl)oxy)trimethylsilane (105762-60-5) + (E)-1,3-diphenyl-1-(trimethylsiloxy)-1-propene (105762-50-3)

Guidance literature:

With lithium diisopropyl amide; In diethyl ether; at -78 - 25 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1021/jo00378a038

Reference yield:

trimethyl<2-(phenylthio)-3-phenylpropanoyl>silane (66132-89-6) → (E)-1,3-diphenyl-1-(trimethylsiloxy)-1-propene (105762-50-3)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether / 1 h / -110 - 0 °C

2: LDA / diethyl ether / -110 °C

With lithium diisopropyl amide; In diethyl ether;

DOI:10.1021/jo00378a038

upstream raw materials:

trimethyl<2-(phenylthio)-3-phenylpropanoyl>silane

phenyllithium

1,3-Diphenyl-2-phenylsulfanyl-1-trimethylsilanyl-propan-1-ol

1-styrenyloxytrimethylsilane

Refernces

• 1、 Reich, Hans J.,Holtan, Ronald C.,Bolm, Carsten. "Acylsilane chemistry. Synthesis of regio- and stereoisomerically defined enol silyl ethers using acylsilanes". . p. 5609 - 5617. Retrieved 2007/10/02.