FULLERENE-C76, 98%

Base Information

• Chemical Name: FULLERENE-C76, 98%
• CAS No.: 142136-39-8
• Molecular Formula: C₇₆
• Molecular Weight: 912.836
• Mol file: 142136-39-8.mol

Synonyms:

Chemical Property of FULLERENE-C76, 98%

Chemical Property:

• Melting Point: >350 °C (lit.)
• Solubility.: organic solvents: soluble

Purity/Quality:

97% ^*data from raw suppliers

Fullerene-C76 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Fullerene-C76 is a higher order fullerene with good optical absorption, which can be potentially used for polymeric solar cells based applications.

Technology Process of FULLERENE-C76, 98%

There total 11 articles about FULLERENE-C76, 98% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

scandium(III) oxide + erbium(III) oxide + graphite → C78 fullerene (190913-68-9,762276-62-0,149821-76-1,143974-29-2,762276-83-5,765901-30-2,762276-97-1,765901-31-3,762276-72-2) + fullerene-C60 (99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0) + [5,6]fullerene-C70 (741268-81-5,741268-84-8,133227-82-4,133320-10-2,133320-11-3,133869-47-3,134054-62-9,134932-61-9,149820-05-3,149820-06-4,157903-26-9,175779-21-2,115383-22-7,958017-68-0,958017-71-5,958017-74-8,958017-77-1,958017-80-6,140630-87-1,140694-21-9,151716-50-6,157008-89-4,220062-79-3,220062-83-9) + [76]fullerene (141197-61-7,358617-42-2,142136-39-8,141197-59-3,149544-69-4,141197-58-2,358617-43-3,358617-44-4,149544-68-3,141197-63-9,165882-45-1,159651-79-3,141197-62-8,141197-60-6,172825-32-0) + fullerene C84 (171229-84-8,149983-29-9,160636-82-8,160636-83-9,159572-90-4,160636-84-0,159572-91-5,145809-20-7)

Guidance literature:

cobalt(II) oxide; In neat (no solvent); vaporization of graphite rods with 2%Sc2O3/3%Er2O3/95% graphite powder (with CoO as catalyst) in Kraetschmer-Huffman fullerene generator under dynamic flow of He and N2; further products; extn. with CS2; purifn. via three stages of HPLC; using CS2 and tolueneas eluant;

DOI:10.1021/ja001984v

Reference yield:

graphite → C78 fullerene (190913-68-9,762276-62-0,149821-76-1,143974-29-2,762276-83-5,765901-30-2,762276-97-1,765901-31-3,762276-72-2) + fullerene + fullerene-C60 (99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0) + [5,6]fullerene-C70 (741268-81-5,741268-84-8,133227-82-4,133320-10-2,133320-11-3,133869-47-3,134054-62-9,134932-61-9,149820-05-3,149820-06-4,157903-26-9,175779-21-2,115383-22-7,958017-68-0,958017-71-5,958017-74-8,958017-77-1,958017-80-6,140630-87-1,140694-21-9,151716-50-6,157008-89-4,220062-79-3,220062-83-9) + [76]fullerene (141197-61-7,358617-42-2,142136-39-8,141197-59-3,149544-69-4,141197-58-2,358617-43-3,358617-44-4,149544-68-3,141197-63-9,165882-45-1,159651-79-3,141197-62-8,141197-60-6,172825-32-0)

Guidance literature:

With Dy; In neat (no solvent); byproducts: C84, C86, DyC82; Electric Arc; Dy/graphite composite rods burned in arc discharge under anaerobic conditions; mixt. of C60, C70, C76, C78, C84, C86, DyC82, C88, C90, C92, C94,C96, C98 obtained; sepd. by chromy.;

DOI:10.1039/b208820g

Reference yield:

graphite → C78 fullerene (190913-68-9,762276-62-0,149821-76-1,143974-29-2,762276-83-5,765901-30-2,762276-97-1,765901-31-3,762276-72-2) + fullerene-C60 (99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0) + [5,6]fullerene-C70 (741268-81-5,741268-84-8,133227-82-4,133320-10-2,133320-11-3,133869-47-3,134054-62-9,134932-61-9,149820-05-3,149820-06-4,157903-26-9,175779-21-2,115383-22-7,958017-68-0,958017-71-5,958017-74-8,958017-77-1,958017-80-6,140630-87-1,140694-21-9,151716-50-6,157008-89-4,220062-79-3,220062-83-9) + [76]fullerene (141197-61-7,358617-42-2,142136-39-8,141197-59-3,149544-69-4,141197-58-2,358617-43-3,358617-44-4,149544-68-3,141197-63-9,165882-45-1,159651-79-3,141197-62-8,141197-60-6,172825-32-0) + fullerene C84 (171229-84-8,149983-29-9,160636-82-8,160636-83-9,159572-90-4,160636-84-0,159572-91-5,145809-20-7)

Guidance literature:

In neat (no solvent); Electric Arc; further products: C104, C60O, C70O; single-stage plasma-arc synthesis with graphite electrodes under He (pressure 300 mm Hg); fullerens extd. with o-xylene; not isolated; spectrophotometry, high-resolution LC-MS;

DOI:10.1134/S1070427207110213

upstream raw materials:

palladium

cerium

pyrographite

nitrogen

Downstream raw materials:

fullerene-C₆₀

[5,6]fullerene-C₇₀

Refernces

• 1、 Liu, Kuang-Shun,Li, Ming-Jhe,Lai, Chien-Chen,Chiu, Sheng-Hsien. "Incarceration of Higher-Order Fullerenes within Cyclotriveratrylene-Based Hemicarcerands Allows Selective Isolation of C76, C78, and C84from a Commercial Fullerene Mixture". supporting information. p. 17468 - 17476. Retrieved 2016/11/23.
• 2、 Simeonov, Kalin S.,Amsharov, Konstantin Yu.,Krokos, Evangelos,Jansen, Martin. "An epilogue on the C78-fullerene family: The discovery and characterization of an elusive isomer". . p. 6283 - 6285. Retrieved 2009/04/07.