Ir(acetylacetonato)(η2-cis-cyclooctene)(tricyclohexylphosphane)

Base Information

Chemical Name:Ir(acetylacetonato)(η2-cis-cyclooctene)(tricyclohexylphosphane)
CAS No.:159565-47-6
Molecular Formula:C₃₁H₅₄IrO₂P
Molecular Weight:681.962
Hs Code.:

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Chemical Property of Ir(acetylacetonato)(η2-cis-cyclooctene)(tricyclohexylphosphane)

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Technology Process of Ir(acetylacetonato)(η2-cis-cyclooctene)(tricyclohexylphosphane)

There total 2 articles about Ir(acetylacetonato)(η2-cis-cyclooctene)(tricyclohexylphosphane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: Ir(CH₃COCHCOCH₃)(C₈H₁₄)2

: 2622-14-2
tricyclohexylphosphine

: 159565-47-6
Ir(cyclooctene)(acac)(tricyclohexylphosphine)

Guidance literature:: In toluene; Ar-atmosphere; stirring (room temp., 5 min); filtering, pptn. on concg. and MeOH addn., decanting, washing (MeOH), drying (vac.); elem. anal.;

Reference yield: 79.0%

: 34766-88-6
(acetylacetonato)bis(η2-cis-cyclooctene)iridium(I)

: 2622-14-2
tricyclohexylphosphine

: 159565-47-6
Ir(acetylacetonato)(η2-cis-cyclooctene)(tricyclohexylphosphane)

Guidance literature:: In toluene; toluene soln. of PCy3 (0.59 mmol) added of toluene soln. of Ir(acac)(η2-coe)2 (0.59 mmol), reaction allowed to proceed for 18 h under N2; solvent removed under vac., residual oil dissolved in minimum volume of hexane, stored at -30°C, ppt. collected by suction filtration, washed with cold hexane; XRD;
DOI:10.1002/ejic.201100057

Reference yield: 93.0%

: 617-86-7
triethylsilane

: 159565-47-6
Ir(cyclooctene)(acac)(tricyclohexylphosphine)

: Ir((CH₃CO)2CH)(H)(Si(C₂H₅)3)(P(C₆H₁₁)3)

Guidance literature:: In toluene; byproducts: cyclooctene; Ar-atmosphere; stirring (room temp., 30 min); filtering, concg., Me2CO addn., crystn. (-20°C, 12 h); elem. anal.;
DOI:10.1021/om950628w