(Pd(C₆H₄CH₂PC(CH₃)3(CH₃C₆H₄))Cl)2

Base Information

• Chemical Name: (Pd(C₆H₄CH₂PC(CH₃)3(CH₃C₆H₄))Cl)2
• CAS No.: 255865-51-1
• Molecular Formula: C₃₆H₄₄Cl₂P₂Pd₂
• Molecular Weight: 822.439
• Mol file: 255865-51-1.mol

Synonyms:

Chemical Property of (Pd(C₆H₄CH₂PC(CH₃)3(CH₃C₆H₄))Cl)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Pd(C₆H₄CH₂PC(CH₃)3(CH₃C₆H₄))Cl)2

There total 5 articles about (Pd(C₆H₄CH₂PC(CH₃)3(CH₃C₆H₄))Cl)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.6%

trans-di(μ-acetato)-bis[o-(tert-butyl-o-tolylphosphino)benzyl]dipalladium(II) (197808-70-1,36007-31-5) + 1,3-di-tert-butyl-1H-imidazol-3-ium chloride (157197-54-1) → trans-di(μ-chloro)-bis[o-(tert-butyl-o-tolylphosphino)benzyl]dipalladium(II) (36007-29-1,849753-57-7,255865-51-1,613238-18-9,255865-38-4)

Guidance literature:

In dimethyl sulfoxide; soln. of imidazolium salt and Pd complex in DMSO was heated at 120°C for 2 h; filtered; washed (DMSO, THF, toluene, hexane);

DOI:10.1016/j.jorganchem.2006.01.018

Reference yield: 71.0%

(R)-di-μ-chlorobis[2-[1-amino-2,2-dimethylpropyl]phenyl-C,N]dipalladium(II) + tert-butyl[bis(2-methylphenyl)]phosphine (36228-06-5) → (Pd(C6H4CH2PC(CH3)3(CH3C6H4))Cl)2 (849753-57-7,613238-18-9,255865-38-4,255865-51-1,36007-29-1)

Guidance literature:

In acetic acid; toluene; mixt. Pd complex and ligand in toluene-AcOH was stirred at 60°C for 1 h;

DOI:10.1007/s11172-006-0573-8

Reference yield: 66.0%

(S(c))-di-μ-chlorobis[2-(1-aminoethyl)phenyl-C,N]dipalladium(II) + tert-butyl[bis(2-methylphenyl)]phosphine (36228-06-5) → (Pd(C6H4CH2PC(CH3)3(CH3C6H4))Cl)2 (613238-18-9,255865-51-1,849753-57-7,36007-29-1,255865-38-4)

Guidance literature:

In toluene; mixt. Pd complex and ligand in toluene was stirred at 20°C for 14days, ppt. was filtered off, washed with PhMe, C6H6, CH2Cl2, mother liq uid was extracted with aq. ethyleneamine, CH2Cl2 and 1M HCl were added; ppt. was filtered, washed with toluene, benzene, and CH2Cl2, extd. with ethylenediamine, CH2Cl2 and 1 M HCl were added, mixt. was chromd. dry column (eluent - Et2O-hexane, from 1:10 to 3:1);

DOI:10.1007/s11172-006-0573-8

upstream raw materials:

trans-di(μ-acetato)-bis[o-(tert-butyl-o-tolylphosphino)benzyl]dipalladium(II)

1,3-di-tert-butyl-1H-imidazol-3-ium chloride

rac-di-μ-chlorobis[2-(1-amino-2,2-dimethylpropyl)phenyl-C,N]dipalladium(II)

tert-butyl[bis(2-methylphenyl)]phosphine