Technology Process of 2,3,4-tri-O-acetyl-N1-benzoyl-5-deoxy-5-methoxycarbonylamino-α-DL-lyxopyranosylamine
There total 8 articles about 2,3,4-tri-O-acetyl-N1-benzoyl-5-deoxy-5-methoxycarbonylamino-α-DL-lyxopyranosylamine which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 99 percent / Pr4NIO4 / CH2Cl2 / 1 h / 0 °C
2: 4.03 g / N-methylmorpholine N-oxide hydrate / OsO4 + t-BuOOH/BuOH / acetone; H2O / 1.) 1 h, 0 deg.C, 2.) room temp.
3: pyridine / Ambient temperature
4: 1.) H2; 2.) Pyridine / 1.) Pd/C / 1.) ethanol, 1 atm., room temp.; 2.) room temp.
With
pyridine; tetrapropylammonium periodate; hydrogen; 4-methylmorpholine N-oxide;
tert.-butylhydroperoxide; palladium on activated charcoal; osmium(VIII) oxide; butan-1-ol;
In
dichloromethane; water; acetone;
DOI:10.1002/hlca.19870700308
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 99 percent / Pr4NIO4 / CH2Cl2 / 1 h / 0 °C
2: 4.03 g / N-methylmorpholine N-oxide hydrate / OsO4 + t-BuOOH/BuOH / acetone; H2O / 1.) 1 h, 0 deg.C, 2.) room temp.
3: pyridine / Ambient temperature
4: 1.) H2; 2.) Pyridine / 1.) Pd/C / 1.) ethanol, 1 atm., room temp.; 2.) room temp.
With
pyridine; tetrapropylammonium periodate; hydrogen; 4-methylmorpholine N-oxide;
tert.-butylhydroperoxide; palladium on activated charcoal; osmium(VIII) oxide; butan-1-ol;
In
dichloromethane; water; acetone;
DOI:10.1002/hlca.19870700308
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 4.03 g / N-methylmorpholine N-oxide hydrate / OsO4 + t-BuOOH/BuOH / acetone; H2O / 1.) 1 h, 0 deg.C, 2.) room temp.
2: pyridine / Ambient temperature
3: 1.) H2; 2.) Pyridine / 1.) Pd/C / 1.) ethanol, 1 atm., room temp.; 2.) room temp.
With
pyridine; hydrogen; 4-methylmorpholine N-oxide;
tert.-butylhydroperoxide; palladium on activated charcoal; osmium(VIII) oxide; butan-1-ol;
In
water; acetone;
DOI:10.1002/hlca.19870700308
