(2R)-2-(2-iodoethyl)-1,2-O-isopropylideneundecane-1,2-diol

Base Information

Chemical Name:(2R)-2-(2-iodoethyl)-1,2-O-isopropylideneundecane-1,2-diol
CAS No.:105376-23-6
Molecular Formula:C₁₆H₃₁IO₂
Molecular Weight:382.325
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R)-2-(2-iodoethyl)-1,2-O-isopropylideneundecane-1,2-diol

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Technology Process of (2R)-2-(2-iodoethyl)-1,2-O-isopropylideneundecane-1,2-diol

There total 8 articles about (2R)-2-(2-iodoethyl)-1,2-O-isopropylideneundecane-1,2-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 105342-58-3
(2R)-1,2-O-isopropylidene-4-O-mesyl-2-nonylbutane-1,2,4-triol

: 105376-23-6
(2R)-2-(2-iodoethyl)-1,2-O-isopropylideneundecane-1,2-diol

Guidance literature:: With sodium iodide; In butanone; Heating;
DOI:10.1039/P19860000581

Reference yield:

: 76853-14-0
2-nonenyl bromide

: 105376-23-6
(2R)-2-(2-iodoethyl)-1,2-O-isopropylideneundecane-1,2-diol

Guidance literature:: Multi-step reaction with 8 steps

1: hexamethylphosphoric triamide, lithium di-isopropylamide / tetrahydrofuran / -78 - -30 °C

2: 90 percent / hydrogen / 10percent Pd-C / methanol

3: 78 percent / acetic acid / H₂O / Heating

4: 89 percent / pyridine / Ambient temperature

5: 1.) lithium triethylborohydride; 2.) 30percent hydrogen peroxide, sodium hydroxide / 1.) THF, from 0 deg C to r. t.; 2.) water from 0 deg C to 50 deg C

6: 76 percent / toluene-p-sulphonic acid / 3 h / Ambient temperature

7: 90 percent / pyridine

8: 93 percent / sodium iodide / butan-2-one / Heating

With pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydroxide; hydrogen; dihydrogen peroxide; lithium triethylborohydride; acetic acid; sodium iodide; lithium diisopropyl amide; palladium on activated charcoal; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; water; butanone;
DOI:10.1039/P19860000581

Reference yield:

: 105342-53-8
dimethyl (2R,3R)-2,3-O-isopropylidene-2-nonyltartrate

: 105376-23-6
(2R)-2-(2-iodoethyl)-1,2-O-isopropylideneundecane-1,2-diol

Guidance literature:: Multi-step reaction with 6 steps

1: 78 percent / acetic acid / H₂O / Heating

2: 89 percent / pyridine / Ambient temperature

3: 1.) lithium triethylborohydride; 2.) 30percent hydrogen peroxide, sodium hydroxide / 1.) THF, from 0 deg C to r. t.; 2.) water from 0 deg C to 50 deg C

4: 76 percent / toluene-p-sulphonic acid / 3 h / Ambient temperature

5: 90 percent / pyridine

6: 93 percent / sodium iodide / butan-2-one / Heating

With pyridine; sodium hydroxide; dihydrogen peroxide; lithium triethylborohydride; acetic acid; sodium iodide; toluene-4-sulfonic acid; In water; butanone;
DOI:10.1039/P19860000581