Al(CH₃)2[1-(N(2,6-i-Pr₂-C₆H₃))-2-(PPh₂=N(2,4,6-Me₃C₆H₂))C₆H₄]

Base Information

Chemical Name:Al(CH₃)2[1-(N(2,6-i-Pr₂-C₆H₃))-2-(PPh₂=N(2,4,6-Me₃C₆H₂))C₆H₄]
CAS No.:676245-94-6
Molecular Formula:C₄₁H₄₈AlN₂P
Molecular Weight:626.801
Hs Code.:

Al(CH<sub>3</sub>)2[1-(N(2,6-i-Pr<sub>2</sub>-C<sub>6</sub>H<sub>3</sub>))-2-(PPh<sub>2</sub>=N(2,4,6-Me<sub>3</sub>C<sub>6</sub>H<sub>2</sub>))C<sub>6</sub>H<sub>4</sub>]

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Chemical Property of Al(CH₃)2[1-(N(2,6-i-Pr₂-C₆H₃))-2-(PPh₂=N(2,4,6-Me₃C₆H₂))C₆H₄]

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Technology Process of Al(CH₃)2[1-(N(2,6-i-Pr₂-C₆H₃))-2-(PPh₂=N(2,4,6-Me₃C₆H₂))C₆H₄]

There total 1 articles about Al(CH₃)2[1-(N(2,6-i-Pr₂-C₆H₃))-2-(PPh₂=N(2,4,6-Me₃C₆H₂))C₆H₄] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 676245-91-3
1-(NH(2,6-i-Pr₂-C₆H₃))-2-(PPh₂=N(2,4,6-Me₃C₆H₂))C₆H₄

: 75-24-1
trimethylaluminum

: 676245-94-6
Al(CH₃)2[1-(N(2,6-i-Pr₂-C₆H₃))-2-(PPh₂=N(2,4,6-Me₃C₆H₂))C₆H₄]

Guidance literature:: In toluene; byproducts: CH4; to a soln. of phosphinimide in toluene was added a toluene soln. of Al(CH3)3 at -23°C, the soln. was stirred for 4 h at 50°C (Ar); evapd. to dryness in vac., the residue was slurried with isopentane, filtered at 23°C, the solid was dried in vac.; elem. anal.;
DOI:10.1021/om034302w

Reference yield: 67.0%

: 676245-94-6
Al(CH₃)2[1-(N(2,6-i-Pr₂-C₆H₃))-2-(PPh₂=N(2,4,6-Me₃C₆H₂))C₆H₄]

: 1109-15-5
tris(pentafluorophenyl)borate

: 676245-97-9
[Al(CH₃)[1-(N(2,6-i-Pr₂-C₆H₃))-2-(PPh₂=N(2,4,6-Me₃C₆H₂))C₆H₄]][MeB(C₆F₅)3]

Guidance literature:: In hexane; hexane soln. of Al-complex was added dropwise to B(C6F5)3 in hexane, cooled to -35°C for 48 h (Ar); supernatant was removed, the solid was dried in vac.; elem. anal.;
DOI:10.1021/om034302w

Reference yield:

: 676245-94-6
Al(CH₃)2[1-(N(2,6-i-Pr₂-C₆H₃))-2-(PPh₂=N(2,4,6-Me₃C₆H₂))C₆H₄]

: trityl tetrakis(pentafluorophenyl)borate

: 676245-98-0
[Al(CH₃)[1-(N(2,6-i-Pr₂-C₆H₃))-2-(PPh₂=N(2,4,6-Me₃C₆H₂))C₆H₄]][B(C₆F₅)4]

Guidance literature:: In further solvent(s); a soln. of Al-complex in C6D5Br was added dropwise to a soln. of B-compound in C6D5Br at -35°C (NMR tube), warmed to -30°C; not sepd., detected by NMR spectra;
DOI:10.1021/om034302w