[phenyl(trimethylsilyl)phosphido]dicarbonyl(η-pentamethylcyclopentadienyl)ruthenium

Base Information

Chemical Name:[phenyl(trimethylsilyl)phosphido]dicarbonyl(η-pentamethylcyclopentadienyl)ruthenium
CAS No.:98526-71-7
Molecular Formula:C₂₁H₂₉O₂PRuSi
Molecular Weight:473.589
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Chemical Property of [phenyl(trimethylsilyl)phosphido]dicarbonyl(η-pentamethylcyclopentadienyl)ruthenium

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Technology Process of [phenyl(trimethylsilyl)phosphido]dicarbonyl(η-pentamethylcyclopentadienyl)ruthenium

There total 2 articles about [phenyl(trimethylsilyl)phosphido]dicarbonyl(η-pentamethylcyclopentadienyl)ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 90420-05-6
{(η5-C5(CH3)5)Ru(CO)2Br}

: 79908-20-6
Lithium(phenyl)(trimethylsilyl)phosphanid

: 98526-71-7
[phenyl(trimethylsilyl)phosphido]dicarbonyl(η-pentamethylcyclopentadienyl)ruthenium

Guidance literature:: In diethyl ether; hexane; a soln. of the phosphide in ether was added dropwise under inert atmosphere to a slurry of Ru-complex in hexane at -30°C, soln. was warmed to room temp., stirring was continued for another 30 min; solvent was removed in vacuo, residue extd. with hexane, ext. filtered,concd., cooled to -25°C for 12 h, crystals were collected by filtration;

Reference yield: 53.0%

: [(C₅(CH₃)5)Ru(carbonyl)3]BF₄

: 79908-20-6
Lithium(phenyl)(trimethylsilyl)phosphanid

: 98526-71-7
[phenyl(trimethylsilyl)phosphido]dicarbonyl(η-pentamethylcyclopentadienyl)ruthenium

Guidance literature:: In diethyl ether; phosphide in Et2O was added dropwise under inert atmosphere to a vigorously stirred suspn. of Ru-complex at -78°C, mixt. was allowed to warm to room temp. within 30 min; solvent was removed in vacuo, residue extd. with hexane, ext. filtered,concd., cooled to -10°C for 12 h, crystals were collected by filtration; elem. anal.;