bis(triphenylphosphine)iminium pentacarbonyl[methoxy(phenyl)(trihydridoborate)acetonitrile]chromium

Base Information

• Chemical Name: bis(triphenylphosphine)iminium pentacarbonyl[methoxy(phenyl)(trihydridoborate)acetonitrile]chromium
• CAS No.: 100218-96-0
• Molecular Formula: C₁₄H₁₁BCrNO₆*C₃₆H₃₀NP₂
• Molecular Weight: 890.64
• Mol file: 100218-96-0.mol

Synonyms:

Chemical Property of bis(triphenylphosphine)iminium pentacarbonyl[methoxy(phenyl)(trihydridoborate)acetonitrile]chromium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(triphenylphosphine)iminium pentacarbonyl[methoxy(phenyl)(trihydridoborate)acetonitrile]chromium

There total 1 articles about bis(triphenylphosphine)iminium pentacarbonyl[methoxy(phenyl)(trihydridoborate)acetonitrile]chromium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

bis(triphenylphosphine)iminium cyanotrihydridoborate (90386-84-8) + pentacarbonyl(1-methoxybenzylidene)chromium(0) (27436-93-7) → bis(triphenylphosphine)iminium pentacarbonyl[methoxy(phenyl)(trihydridoborate)acetonitrile]chromium (100218-96-0)

Guidance literature:

In dichloromethane; PPN(NCBH3) in CH2Cl2 was added portionwise at -30°C under N2 to a soln. of carbene complex in CH2Cl2, mixt. was stirred for 1 h at -30°C; solvent was removed under high vac., residue chromd. over Kieselgel at -30°C (eluent Et2O followed by 10:1 Et2O-MeOH), recrystd. from THF-pentane; elem. anal.;

DOI:10.1016/0022-328X(85)87231-4

upstream raw materials:

bis(triphenylphosphine)iminium cyanotrihydridoborate

pentacarbonyl(1-methoxybenzylidene)chromium⁽⁰⁾

Refernces