[((C₆H₅)3P)2PdGe(N(Si(CH₃)3)2)2]

Base Information

• Chemical Name: [((C₆H₅)3P)2PdGe(N(Si(CH₃)3)2)2]
• CAS No.: 479072-96-3
• Molecular Formula: C₄₈H₆₆GeN₂P₂PdSi₄
• Molecular Weight: 1024.36
• Mol file: 479072-96-3.mol

Synonyms:

Chemical Property of [((C₆H₅)3P)2PdGe(N(Si(CH₃)3)2)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [((C₆H₅)3P)2PdGe(N(Si(CH₃)3)2)2]

There total 3 articles about [((C₆H₅)3P)2PdGe(N(Si(CH₃)3)2)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

tetrakis(triphenylphosphine) palladium(0) (14221-01-3) + bis[bis(trimethylsilyl)amino]germanium(II) (59863-12-6) → [((C6H5)3P)2PdGe(N(Si(CH3)3)2)2] (479072-96-3)

Guidance literature:

In benzene; byproducts: PPh3; air-free technique; mixt. was stirred for 5 h; volatiles were evapd., additional Ge ligand was added to the residue, mixt. was then recrystd. from THF/MeCN; elem. anal.;

DOI:10.1021/om0204134

Reference yield:

[(Ph3P)2Pd(μS)2Ge(N(SiMe3)2)2] (625385-24-2) + bis[bis(trimethylsilyl)amino]germanium(II) (59863-12-6) → [((C6H5)3P)2PdGe(N(Si(CH3)3)2)2] (479072-96-3)

Guidance literature:

In benzene-d6; Irradiation (UV/VIS); air-free technique; soln. of Pd complex and germylene (5 equiv.) in benzene-d6 was irradiated for 2 d; NMR monitoring;

DOI:10.1021/ic034613z

Reference yield:

[(Ph3P)2Pd(μS)2Ge(N(SiMe3)2)2] (625385-24-2) + bis[bis(trimethylsilyl)amino]germanium(II) (59863-12-6) → bis(bistrimethylsilylamido)germanium(IV) sulphide (136492-96-1) + [((C6H5)3P)2PdGe(N(Si(CH3)3)2)2] (479072-96-3)

Guidance literature:

In benzene-d6; air-free technique; soln. of Pd complex and germylene (5 equiv.) in benzene-d6 was heated at 63°C for 48 h; NMR monitoring;

DOI:10.1021/ic034613z

upstream raw materials:

[(Ph3P)2Pd(μS)2Ge(N(SiMe3)2)2]

bis[bis(trimethylsilyl)amino]germanium(II)

tetrakis(triphenylphosphine) palladium⁽⁰⁾

Downstream raw materials:

[(Ph3P)2Pd(μS)2Ge(N(SiMe3)2)2]

((C₆H₅)3P)2Pd(O₂)Ge[N(Si(CH₃)3)2]2