[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]Zr(⁽¹³⁾CH₃)2

Base Information

Chemical Name:[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]Zr(⁽¹³⁾CH₃)2
CAS No.:318472-53-6
Molecular Formula:C₂₄H₃₇N₃Zr
Molecular Weight:460.78
Hs Code.:

[(2,4,6-Me<sub>3</sub>C<sub>6</sub>H<sub>2</sub>NCH<sub>2</sub>CH<sub>2</sub>)2NH]Zr(<sup>(13)</sup>CH<sub>3</sub>)2

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Chemical Property of [(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]Zr(⁽¹³⁾CH₃)2

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Technology Process of [(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]Zr(⁽¹³⁾CH₃)2

There total 1 articles about [(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]Zr(⁽¹³⁾CH₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 236111-38-9
mer-[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]ZrMe₂

: 105176-13-4
[13C]methylmagnesium iodide

: 318472-53-6
[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]Zr(⁽¹³⁾CH₃)2

Guidance literature:: In diethyl ether; under N2, 2.3 M Et2O soln. of Mg-compd. was added to Et2O suspn. of Zr-compd. at -30 °C, stirring for 20 min without cooling; solvent was removed in vac., residue was dissolved in toluene, 1,4-dioxane was added, mixt. was filtered through Celite, solvent was removed in vac., recrystn. from mixt. of ether and pentane at -30 °C;
DOI:10.1021/om0004996

Reference yield: 81.0%

: 4227-95-6
[13C]methyl iodide

: 318472-53-6
[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]Zr(⁽¹³⁾CH₃)2

: 917-54-4
methyllithium

: [(2,4,6-Me₃C₆H₂NCH₂CH₂)2N⁽¹³⁾CH₃]Zr(⁽¹³⁾CH₃)2

Guidance literature:: In diethyl ether; byproducts: CH4; under N2, 1.6 M Et2O soln. of LiMe was added to Et2O suspn. of Zr-compd., stirring for 20 min, temp. was allowed to increase to room temp., soln. was cooled to -30 °C, (13)CH3I was added, stirring for 30 min; solvent was removed in vac., residue was extd. with toluene, toluene wasremoved in vac., solid was washed with cold pentane, dried in vac.;
DOI:10.1021/om0004996

Reference yield:

: 318472-53-6
[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NH]Zr(⁽¹³⁾CH₃)2

: trityl tetrakis(pentafluorophenyl)borate

: 318472-68-3
[(2,4,6-Me₃C₆H₂NCH₂CH₂)2NHZr⁽¹³⁾CH₃]B(C₆F₅)4

Guidance literature:: In further solvent(s); byproducts: Ph3C(13)CH3; under N2, C6D5Br as solvent, equimolar amt. of reagents, -30 °C;
DOI:10.1021/om0004996