[Fe(C₅H₅)(C₅H₄CCCCCCRu(C₅H₅)((C₆H₅)2PCH₂CH₂P(C₆H₅)2))]

Base Information

• Chemical Name: [Fe(C₅H₅)(C₅H₄CCCCCCRu(C₅H₅)((C₆H₅)2PCH₂CH₂P(C₆H₅)2))]
• CAS No.: 942131-70-6
• Molecular Formula: C₄₇H₃₈FeP₂Ru
• Molecular Weight: 821.683
• Mol file: 942131-70-6.mol

Synonyms:

Chemical Property of [Fe(C₅H₅)(C₅H₄CCCCCCRu(C₅H₅)((C₆H₅)2PCH₂CH₂P(C₆H₅)2))]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe(C₅H₅)(C₅H₄CCCCCCRu(C₅H₅)((C₆H₅)2PCH₂CH₂P(C₆H₅)2))]

There total 1 articles about [Fe(C₅H₅)(C₅H₄CCCCCCRu(C₅H₅)((C₆H₅)2PCH₂CH₂P(C₆H₅)2))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) + [Fe(C5H5)(C5H4CCCCCCSi(CH3)3)] (942131-68-2) → [Fe(C5H5)(C5H4CCCCCCRu(C5H5)((C6H5)2PCH2CH2P(C6H5)2))] (942131-70-6)

Guidance literature:

With 1,5-diazabicyclo[5.4.0]undec-5-ene; water; KF; In methanol; under N2; soln. of Fe complex in MeOH contg. H2O and DBU (1 drop) added to mixt. of Ru complex and KF under stirring, mixt. refluxed for 1 h; cooled, ppt. collected, dried in vacuo, column chromy. (basic alumina, benzene); elem. anal.;

DOI:10.1016/j.jorganchem.2007.02.043

Reference yield: 91.0%

[Fe(C5H5)(C5H4CCCCCCRu(C5H5)((C6H5)2PCH2CH2P(C6H5)2))] (942131-70-6) + Co2(CO)6(bis(diphenylphosphanyl)methane) → FcC2(Co2(μ-dppm)(CO)4)CCCCRu(dppe)Cp

Guidance literature:

In tetrahydrofuran; under N2; soln. of Fe-Ru complex and Co2(CO)6(dppm) in THF refluxed overnight; evapd. under vac., prep. TLC (hexane/acetone 3/2); elem. anal.;

DOI:10.1016/j.jorganchem.2007.02.043

Reference yield: 65.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + [Fe(C5H5)(C5H4CCCCCCRu(C5H5)((C6H5)2PCH2CH2P(C6H5)2))] (942131-70-6) → ((C5H5)Ru((C6H5)2PCH2CH2P(C6H5)2)CCC2Co2(CO)6C2Co2(CO)6C5H4)Fe(C5H5)

Guidance literature:

In tetrahydrofuran; under N2; soln. of Fe-Ru complex and Co2(CO)8 in THF stirred overnight; evapd. under vac., prep. TLC (hexane/acetone 2/1); elem. anal.;

DOI:10.1016/j.jorganchem.2007.02.043

upstream raw materials:

[Fe(C₅H₅)(C₅H₄CCCCCCSi(CH₃)3)]

Downstream raw materials:

[Fe(C₅H₅)(C₅H₄CCCC(C₄(CN)4)Ru(C₅H₅)((C₆H₅)2PCH₂CH₂P(C₆H₅)2))]