chlorodi(η(5)-cyclopentadienyl)(1,1-dimesityl-3,3-dimethyl-1-butenyloxy)titanium(IV)

Base Information

• Chemical Name: chlorodi(η(5)-cyclopentadienyl)(1,1-dimesityl-3,3-dimethyl-1-butenyloxy)titanium(IV)
• CAS No.: 187731-57-3
• Molecular Formula: C₃₄H₄₁ClOTi
• Molecular Weight: 549.032
• Mol file: 187731-57-3.mol

Synonyms:

Chemical Property of chlorodi(η(5)-cyclopentadienyl)(1,1-dimesityl-3,3-dimethyl-1-butenyloxy)titanium(IV)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chlorodi(η(5)-cyclopentadienyl)(1,1-dimesityl-3,3-dimethyl-1-butenyloxy)titanium(IV)

There total 1 articles about chlorodi(η(5)-cyclopentadienyl)(1,1-dimesityl-3,3-dimethyl-1-butenyloxy)titanium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

bis(cyclopentadienyl)titanium dichloride (1271-19-8) + 1,1-dimesityl-3,3-dimethylbuten-2-ol (89959-16-0) → chlorodi(η(5)-cyclopentadienyl)(1,1-dimesityl-3,3-dimethyl-1-butenyloxy)titanium(IV) (187731-57-3)

Guidance literature:

With NaH; In tetrahydrofuran; (argon); addn. of the ethenol to NaH in THF at room temp., stirring (1 h), filtration, addn. to the Ti complex in THF at room temp., stirring (12 h); solvent removal (vac.), extn. (Et2O), filtration, extn. (CH2Cl2), concn., pptn. with n-hexane, filtration, crystn. on storage at -40°C; elem. anal.;

DOI:10.1002/cber.19971300209

upstream raw materials:

bis(cyclopentadienyl)titanium dichloride

1,1-dimesityl-3,3-dimethylbuten-2-ol