(E)-(S)-3-Isopropyl-3-phenyl-hex-4-enoic acid ethyl ester

Base Information

Chemical Name:(E)-(S)-3-Isopropyl-3-phenyl-hex-4-enoic acid ethyl ester
CAS No.:1026166-16-4
Molecular Formula:C₁₇H₂₄O₂
Molecular Weight:260.376
Hs Code.:

Synonyms:

Suppliers and Price of (E)-(S)-3-Isopropyl-3-phenyl-hex-4-enoic acid ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (E)-(S)-3-Isopropyl-3-phenyl-hex-4-enoic acid ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (E)-(S)-3-Isopropyl-3-phenyl-hex-4-enoic acid ethyl ester

There total 7 articles about (E)-(S)-3-Isopropyl-3-phenyl-hex-4-enoic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 92421-14-2
trans-3-Phenyl-4-methyl-2-penten-1-al

: 1026166-16-4
(E)-(S)-3-Isopropyl-3-phenyl-hex-4-enoic acid ethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 27.6 g / diethyl ether / 2 h

2: 42 percent / Burkholderia cepacia lipase / diethyl ether; various solvent(s)

3: 93 percent / aq. KOH / ethanol / 4 h / Heating

4: propionic acid / 150 °C

With Burkholderia cepacia lipase; potassium hydroxide; propionic acid; In diethyl ether; ethanol; 4: Claisen-Johnson rearrangement;
DOI:10.1055/s-2005-861856

Reference yield:

: 62751-30-8,126275-04-5,62713-10-4
(E)-ethyl 4-methyl-3-phenylpent-2-enoate

: 1026166-16-4
(E)-(S)-3-Isopropyl-3-phenyl-hex-4-enoic acid ethyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: Red-Al / tetrahydrofuran; toluene / 20 °C

2: MnO₂ / CH₂Cl₂ / 24 h / 20 °C

3: 27.6 g / diethyl ether / 2 h

4: 42 percent / Burkholderia cepacia lipase / diethyl ether; various solvent(s)

5: 93 percent / aq. KOH / ethanol / 4 h / Heating

6: propionic acid / 150 °C

With Burkholderia cepacia lipase; manganese(IV) oxide; potassium hydroxide; propionic acid; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; toluene; 6: Claisen-Johnson rearrangement;
DOI:10.1055/s-2005-861856

Reference yield:

: 611-70-1
phenyl isopropyl ketone

: 1026166-16-4
(E)-(S)-3-Isopropyl-3-phenyl-hex-4-enoic acid ethyl ester

Guidance literature:: Multi-step reaction with 7 steps

1.1: NaH / toluene / 1 h / Heating

1.2: 41.5 percent / tetrahydrofuran / 14 h / Heating

2.1: Red-Al / tetrahydrofuran; toluene / 20 °C

3.1: MnO₂ / CH₂Cl₂ / 24 h / 20 °C

4.1: 27.6 g / diethyl ether / 2 h

5.1: 42 percent / Burkholderia cepacia lipase / diethyl ether; various solvent(s)

6.1: 93 percent / aq. KOH / ethanol / 4 h / Heating

7.1: propionic acid / 150 °C

With Burkholderia cepacia lipase; manganese(IV) oxide; potassium hydroxide; sodium hydride; propionic acid; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; toluene; 1.2: Horner-Emmons olefination / 7.1: Claisen-Johnson rearrangement;
DOI:10.1055/s-2005-861856