Technology Process of [CH(3,5-Me2Pz)2-κ3-[N,C,N]]W(carbonyl)3(triphenylstannyl)
There total 1 articles about [CH(3,5-Me2Pz)2-κ3-[N,C,N]]W(carbonyl)3(triphenylstannyl) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
THF;
Irradiation (UV/VIS); under Ar; ligand added to soln. of W(CO)5THF in THF, prepd. in situ by the irradn. of soln. of W(CO)6 in THF for 8 h; mixt. stirred and heated at reflux for 2 h; solvent removed under reduced pressure; residual solid purified by column chromy. (alumina, CH2Cl2/hexane (1:2 v/v)); eluate concd. to dryness; residual solid recrystd. from CH2Cl2/hexane; elem. anal.;
DOI:10.1021/om030221o
- Guidance literature:
-
In
dichloromethane;
under Ar atm. HCl was bubbled for 5 min through soln. W complex in CH2Cl2; solvent was removed in vacuo, chromy. on silica (CH2Cl2), soln. was concd. in vacuo, recrystn. from CH2Cl2-hexane; elem. anal.;
DOI:10.1021/om0503895
- Guidance literature:
-
In
dichloromethane;
under Ar atm. HBr was bubbled for 2 h through soln. W complex in CH2Cl2; solvent was removed in vacuo, chromy. on silica (CH2Cl2), soln. was concd. in vacuo, recrystn. from CH2Cl2-hexane; elem. anal.;
DOI:10.1021/om0503895
