trans-[Pd(Fmes)2(SMe₂)2]

Base Information

Chemical Name:trans-[Pd(Fmes)2(SMe₂)2]
CAS No.:801319-55-1
Molecular Formula:C₂₂H₁₆F₁₈PdS₂
Molecular Weight:792.892
Hs Code.:

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Chemical Property of trans-[Pd(Fmes)2(SMe₂)2]

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Technology Process of trans-[Pd(Fmes)2(SMe₂)2]

There total 1 articles about trans-[Pd(Fmes)2(SMe₂)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 914979-24-1,14567-23-8,18534-70-8
dichlorobis (dimethyl sulfide) palladium (II)

: 444-40-6
2,4,6-tris(trilfuoromethyl)phenyllithium

: 801319-55-1
trans-[Pd(Fmes)2(SMe₂)2]

: 681294-36-0
trans-[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(SMe₂)2]

: 681459-85-8,681294-32-6
[Pd(μ-Cl)(2,4,6-tris(trifluoromethyl)phenyl)(SMe2)]2

Guidance literature:: With H₂O; In diethyl ether; all manipulations under dry N2; Pd compd. added to org. compd. in Et2O, maintained at 40°C for 24 h, 2 drops of H2O added; volatiles removed in vac., extd. with toluene, filtered, evapd., mixt. of compds. crystd., rest of residue extd. with CH2Cl2, filtered, evapd., recrystd. from CH2Cl2/hexane at -20°C, decanted, washed with hexane, dried in vac., elem. anal.;
DOI:10.1002/ejic.200300229

Reference yield: 83.0%

: 801319-55-1
trans-[Pd(Fmes)2(SMe₂)2]

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 801319-58-4
trans-[Pd(2,4,6-tris(trifluoromethyl)phenyl)2(t-BuNC)2]

Guidance literature:: In toluene; under dry N2, Schlenk setup, metal complex (0.1 mmol) mixed with ligand (2 mmol), refluxed for 5 h; filtered (dry Celite), evapd. (vac.), residue washed (hexane), dried (vac.), recrystd. (CH2Cl2/hexane), elem. anal.;
DOI:10.1002/ejic.200300756

Reference yield: 79.0%

: 1762-34-1
5,5'-dimethyl-2,2'-bipyridine

: 801319-55-1
trans-[Pd(Fmes)2(SMe₂)2]

: [Pd(2,4,6-tris(trifluoromethyl)phenyl)2(4,4'-dimethyl-2,2'-bipyridine)]

Guidance literature:: In toluene; under dry N2, Schlenk setup, ligand (0.2 mmol) added to metal complex (0.1 mmol), refluxed for 7 h; filtered (dry Celite), evapd. (vac.), residue washed (hexane), dried (vac.), recrystd. (acetone/hexane), elem. anal.;
DOI:10.1002/ejic.200300756