Rhodium(1+), (butanenitrile)carbonylbis(triphenylphosphine)-,perchlorate

Base Information

• Chemical Name: Rhodium(1+), (butanenitrile)carbonylbis(triphenylphosphine)-,perchlorate
• CAS No.: 105877-18-7
• Molecular Formula: C₄₁H₃₇NOP₂Rh*ClO₄
• Molecular Weight: 824.054
• Mol file: 105877-18-7.mol

Synonyms:

Chemical Property of Rhodium(1+), (butanenitrile)carbonylbis(triphenylphosphine)-,perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Rhodium(1+), (butanenitrile)carbonylbis(triphenylphosphine)-,perchlorate

There total 1 articles about Rhodium(1+), (butanenitrile)carbonylbis(triphenylphosphine)-,perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

propyl cyanide (109-74-0) + Rh(ClO4)(CO)(PPh3)2 (32354-26-0,36593-52-9) → {Rh(CH3(CH2)2CN)(CO)(P(C6H5)3)2}(1+)*ClO4(1-)={Rh(CH3(CH2)2CN)(CO)(P(C6H5)3)2}ClO4 (105877-18-7)

Guidance literature:

In benzene; addn. of one drop of nitrile to Pt complex soln. under N2, 25°C; crystn. within 5 min; filtration, washing (benzene, hexane); drying in vac.; elem. anal.;

DOI:10.1016/S0277-5387(00)83511-1

upstream raw materials:

propyl cyanide

Rh(ClO₄)(CO)(PPh₃)2