(phenyldibenzophosphole)pentacarbonyltungsten⁽⁰⁾

Base Information

Chemical Name:(phenyldibenzophosphole)pentacarbonyltungsten⁽⁰⁾
CAS No.:71248-95-8
Molecular Formula:C₂₃H₁₃O₅PW
Molecular Weight:584.177
Hs Code.:

(phenyldibenzophosphole)pentacarbonyltungsten<sup>(0)</sup>

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (phenyldibenzophosphole)pentacarbonyltungsten⁽⁰⁾

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Technology Process of (phenyldibenzophosphole)pentacarbonyltungsten⁽⁰⁾

There total 3 articles about (phenyldibenzophosphole)pentacarbonyltungsten⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 14040-11-0
tungsten hexacarbonyl

: 1088-00-2
9-phenyl-9-phosphafluorene

: 71248-95-8
(phenyldibenzophosphole)pentacarbonyltungsten⁽⁰⁾

: 114860-49-0
cis-bis(phenyldibenzophosphole)tetracarbonyltungsten⁽⁰⁾

Guidance literature:: In diethylene glycol dimethyl ether; A mixture of W(CO)6 and DBP in diglyme is refluxed for 4 h (N2).; Cooling, evapn. with heat, addn. of MeOH , column chromy. (silica gel, CH2Cl2 /hexane), recrystn. from CH2Cl2/methanol yields pentacarbonyl complex, elem. anal.;
DOI:10.1021/om00098a006

Reference yield: 26.0%

: C₁₇H₉O₅PW

: 591-51-5
phenyllithium

: 71248-95-8
(phenyldibenzophosphole)pentacarbonyltungsten⁽⁰⁾

Guidance literature:: C₁₇H₉O₅PW; With sodium hydride; In tetrahydrofuran; at -78 - 20 ℃; for 0.333333h; Inert atmosphere; Schlenk technique;

With bromocyane; In tetrahydrofuran; at -78 - 20 ℃; for 0.333333h; Inert atmosphere; Schlenk technique;

phenyllithium; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere; Schlenk technique;
DOI:10.1002/anie.201410603

Reference yield: 10.0%

: 14040-11-0
tungsten hexacarbonyl

: 1088-00-2
9-phenyl-9-phosphafluorene

: 71248-95-8
(phenyldibenzophosphole)pentacarbonyltungsten⁽⁰⁾

: 114925-28-9
fac-tris(phenyldibenzophosphole)tricarbonyltungsten⁽⁰⁾*methanol

: 114860-49-0
cis-bis(phenyldibenzophosphole)tetracarbonyltungsten⁽⁰⁾

Guidance literature:: sodium tetrahydroborate; In ethanol; Refluxing a mixture of W(CO)6 and DBP in EtOH for 10 h (N2), followed by cooling with stirring for 12 h.; Evapn., recrystn. from CH2Cl2/MeOH yields tricarbonyl complex, elem. anal.;
DOI:10.1021/om00098a006