cis-bis(triphenylphosphine)bromo(3-bromobicyclo[2.2.1]hept-2-en-2-yl)platinum(II)

Base Information

Chemical Name:cis-bis(triphenylphosphine)bromo(3-bromobicyclo[2.2.1]hept-2-en-2-yl)platinum(II)
CAS No.:87583-21-9
Molecular Formula:C₄₃H₃₈Br₂P₂Pt
Molecular Weight:971.61
Hs Code.:

Synonyms:

Suppliers and Price of cis-bis(triphenylphosphine)bromo(3-bromobicyclo[2.2.1]hept-2-en-2-yl)platinum(II)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of cis-bis(triphenylphosphine)bromo(3-bromobicyclo[2.2.1]hept-2-en-2-yl)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of cis-bis(triphenylphosphine)bromo(3-bromobicyclo[2.2.1]hept-2-en-2-yl)platinum(II)

There total 4 articles about cis-bis(triphenylphosphine)bromo(3-bromobicyclo[2.2.1]hept-2-en-2-yl)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.0%

: 26026-46-0,18517-48-1,16242-58-3
cis-[PtBr₂(PPh₃)2]

: 75267-72-0
2,3-dibromobicyclo[2.1.1]hept-2-ene

: 87583-21-9
cis-bis(triphenylphosphine)bromo(3-bromobicyclo[2.2.1]hept-2-en-2-yl)platinum(II)

Guidance literature:: With n-C₄H₉Li; In tetrahydrofuran; hexane; toluene; C7H8Br2 soln. in THF under Ar cooled to -78°C, treated with n-C4H9Li in hexane, after 1 h soln. transferrred to suspn. of complex in toluene under Ar, reacted for 2 h at room temp.; H2O added, layers sepd., aq. soln. extd. with ether, combined org. phases dried over MgSO4, filtered, concd. in vac., recrystd. (THF/hexane); elem. anal.;
DOI:10.1021/om00079a022

Reference yield:

: Pt(PPh₃)3(C₂H₄)

: 87583-21-9
cis-bis(triphenylphosphine)bromo(3-bromobicyclo[2.2.1]hept-2-en-2-yl)platinum(II)

Guidance literature:: Multi-step reaction with 2 steps

1: toluene

2: tetrahydrofuran; ethanol

In tetrahydrofuran; ethanol; toluene;
DOI:10.1021/om00079a022