{FePdPt((C₆H₅)2PCH₂P(C₆H₅)2)2(CO)4}

Base Information

Chemical Name:{FePdPt((C₆H₅)2PCH₂P(C₆H₅)2)2(CO)4}
CAS No.:87564-92-9
Molecular Formula:C₅₄H₄₄FeO₄P₄PdPt
Molecular Weight:1238.18
Hs Code.:

{FePdPt((C<sub>6</sub>H<sub>5</sub>)2PCH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)2(CO)4}

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Chemical Property of {FePdPt((C₆H₅)2PCH₂P(C₆H₅)2)2(CO)4}

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Technology Process of {FePdPt((C₆H₅)2PCH₂P(C₆H₅)2)2(CO)4}

There total 5 articles about {FePdPt((C₆H₅)2PCH₂P(C₆H₅)2)2(CO)4} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: disodium tetracarbonylferrate

: 82307-36-6
{PdPtCl₂(dppm)2}

: 87564-91-8,87564-92-9
{FePdPt((C₆H₅)2PCH₂P(C₆H₅)2)2(CO)4}

Guidance literature:: In tetrahydrofuran; cooling Na2Fe(CO)4 (50% excess) and (PtPd((C6H5)2PCH2P(C6H5)2)2Cl2) to -78°C (Ar-atmosphere); addn. of THF (-78°C); warming to -200°C with stirring (24 h); concg., addn. of pentane (-78°C) with stirring;; pptn.; workup below -40°C; elem. anal., 31P-NMR;;

Reference yield:

: 110790-43-7,82307-36-6
{PdPtCl2(μ-dppm)2}

: 56791-54-9
N(P(C₆H₅)3)2⁽¹⁺⁾*(HFe(CO)4)^(1-)=[(C₆H₅)3PNP(C₆H₅)3][HFe(CO)4]

: 87564-91-8,87564-92-9
{FePdPt((C₆H₅)2PCH₂P(C₆H₅)2)2(CO)4}

: 87564-91-8
{FePdPt((C₆H₅)2PCH₂P(C₆H₅)2)2(CO)4}

Guidance literature:: In tetrahydrofuran; byproducts: [(C6H5)3PNP(C6H5)3]Cl; (under N2) THF is added at 25°C to a solid mixt. of PdPt-complexand (Ph3PNPPh3)(HFe(CO)4, mixt. is heated and stirred at 60°C for 2 h; solid is filtered, washed with THF and then with MeOH, filtrate is evaporated, residue is extracted with toluene, evapn., recrystn. from CH2Cl2/hexane, mixt. of isomers with 82% total yield, identified by IR and (31)P NMR;
DOI:10.1016/S0022-328X(00)99783-3

Reference yield:

: 82307-36-6
{PdPtCl₂(dppm)2}

: 2Na⁽¹⁺⁾*Fe(CO)4^(2-)*1.5C₄H₈O=Na₂(Fe(CO)4)*1.5C₄H₈O

: 87564-91-8,87564-92-9
{FePdPt((C₆H₅)2PCH₂P(C₆H₅)2)2(CO)4}

: 87564-91-8
{FePdPt((C₆H₅)2PCH₂P(C₆H₅)2)2(CO)4}

Guidance literature:: In tetrahydrofuran; total yield >80%; product proved to be an unseparable 1:1 mixt. of the two isomeric complexes identified by (1)H, (31)P, (195)Pt NMR and IR spectral data;
DOI:10.1016/S0022-328X(00)99243-X