1,2-(4'-CF₃C₆F₄)2-1,2-closo-C₂B₁₀H₁₀)

Base Information

Chemical Name:1,2-(4'-CF₃C₆F₄)2-1,2-closo-C₂B₁₀H₁₀)
CAS No.:1304037-86-2
Molecular Formula:C₁₆H₁₀B₁₀F₁₄
Molecular Weight:576.343
Hs Code.:

1,2-(4'-CF<sub>3</sub>C<sub>6</sub>F<sub>4</sub>)2-1,2-closo-C<sub>2</sub>B<sub>10</sub>H<sub>10</sub>)

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Chemical Property of 1,2-(4'-CF₃C₆F₄)2-1,2-closo-C₂B₁₀H₁₀)

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Technology Process of 1,2-(4'-CF₃C₆F₄)2-1,2-closo-C₂B₁₀H₁₀)

There total 1 articles about 1,2-(4'-CF₃C₆F₄)2-1,2-closo-C₂B₁₀H₁₀) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 16872-09-6
1,2-dicarba-closo-dodecaborane⁽¹²⁾

: 434-64-0
perfluorotoluene

: 1304037-86-2
1,2-(4'-CF₃C₆F₄)2-1,2-closo-C₂B₁₀H₁₀)

Guidance literature:: With n-BuLi; In tetrahydrofuran; under N2; B compd. dissolved in dry degassed THF; treated with n-BuLi at0°C; stirred for 2 h; warmed to room temp.; cooled to 0°C ; C6F5CF3 added; stirred at room temp. for 18 h; satd. aq. NH4Cl added; aq. layer washed with Et2O; combined org. fractions concd. under reduced pressure; filtered through pad of silica with petroleum ether; soln. concd. under reduced pressure; oil crystd. slowly at room temp.; elem. anal.;
DOI:10.1039/c0dt01798a

Reference yield: 24.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 1304037-86-2
1,2-(4'-CF₃C₆F₄)2-1,2-closo-C₂B₁₀H₁₀)

: sodium pentamethylcyclopentadienide

: 7646-79-9,14543-09-0,16413-89-1
cobalt(II) chloride

: 1-(4'-F₃CC₆F₄)-2,8-Cp*2-12-THF-2,8,1-closo-Co₂CB₉H₈

: 1,12-(4'-CF₃C₆F₄)2-4-C₅Me₅-4,1,12-closo-CoC₂B₁₀H₁₀

: 1334793-89-3
1,2-(4'-F₂(C₅Me₅)CC₆F₄)2-1,2-closo-C₂B₁₀H₁₀

Guidance literature:: With sodium naphthalenide; air; In tetrahydrofuran; react. a soln. of boron compd. in THF with sodium naphthalenide in THF, addn. of Cp*Na in THF, then CoCl2, stirring at room temp. for 18 h, addn. of air for 30 min; evapn. in vac., washing with petroleum ether, column chromy. (silica, CH2Cl2/petroleum ether 1:1), preparative TLC (CH2Cl2/petroleum ether 2:3);elem. anal.;
DOI:10.1021/om200691z

Reference yield: 16.0%

: 1304037-86-2
1,2-(4'-CF₃C₆F₄)2-1,2-closo-C₂B₁₀H₁₀)

: sodium cyclopentadienide

: 7646-79-9,14543-09-0,16413-89-1
cobalt(II) chloride

: 1,12-(4'-CF₃C₆F₄)2-4-C₅H₅-4,1,12-closo-CoC₂B₁₀H₁₀

Guidance literature:: With sodium naphthalenide; air; In tetrahydrofuran; byproducts: naphthalene; react. a soln. of boron compd. in THF with sodium naphthalenide in tHF at 0°C, addn. of CpNa in THF, then CoCl2, heating to reflux, addn.of air for 30 min; evapn. in vac., extn. with CH2Cl2, filtration, evapn. in vac., washing with petroleum ether, preparative TLC (CH2Cl2/petroleum ether 2:5);
DOI:10.1021/om200691z