trans-carbonyl(3-fluorobenzoato)bis(tricyclohexylphosphine)rhodium

Base Information

• Chemical Name: trans-carbonyl(3-fluorobenzoato)bis(tricyclohexylphosphine)rhodium
• CAS No.: 112836-45-0
• Molecular Formula: C₄₄H₇₀FO₃P₂Rh
• Molecular Weight: 830.889
• Mol file: 112836-45-0.mol

Synonyms:

Chemical Property of trans-carbonyl(3-fluorobenzoato)bis(tricyclohexylphosphine)rhodium

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-carbonyl(3-fluorobenzoato)bis(tricyclohexylphosphine)rhodium

There total 2 articles about trans-carbonyl(3-fluorobenzoato)bis(tricyclohexylphosphine)rhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

dodecacarbonyltetrarhodium(0) (494804-05-6) + 3-fluorobenzoic acid (455-38-9) + tricyclohexylphosphine (2622-14-2) → carbonyl(3-fluorobenzoato)bis(tricyclohexylphosphine)rhodium(I) (103948-61-4,112836-45-0)

Guidance literature:

In further solvent(s); High Pressure; Rh compd., phosphine and fluorobenzoic acid were heated at 220°C under pressure of 500 bar for 2 h in tetraglyme; crystals formed by standing of soln. at 0°C overnight; elem. anal.;

DOI:10.1016/0304-5102(87)87026-8

Reference yield: 68.0%

dodecacarbonyltetrarhodium(0) (494804-05-6) + 3-fluorobenzoic acid (455-38-9) + tricyclohexylphosphine (2622-14-2) → trans-carbonyl(3-fluorobenzoato)bis(tricyclohexylphosphine)rhodium (112836-45-0,103948-61-4)

Guidance literature:

In further solvent(s); under N2, to soln. of Rh4(CO)12 in 1,3-dimethylimidazolidin-2-one P(C6H11)3 and FC6H4COOH added, mixed for 5 h at room temp.; crystals collected, washed with cold Et2O, dried in vac., recrystd. at 0°C from toluene-hexane; elem. anal.;

DOI:10.1039/DT9870002969

Reference yield:

trans-carbonyl(3-fluorobenzoato)bis(tricyclohexylphosphine)rhodium (112836-45-0,103948-61-4) + bis(triphenylphosphoranylidene)-ammonium acetate → rhodium(carbonyl)4 (44797-04-8) + bis(triphenylphosphine)iminium tricarbonyl(tricyclohexylphosphine)rhodate

Guidance literature:

With carbon monoxide; hydrogen; In N,N,N,N,N,N-hexamethylphosphoric triamide; in hexamethylphosphoramide; CO:H2 (1:1), atm. pressure; 20°C; inpresense equimolar amt. of (N(PPh3)2)(MeCO2); detected by IR; Kinetics;

DOI:10.1039/DT9870002969

upstream raw materials:

dodecacarbonyltetrarhodium⁽⁰⁾

3-fluorobenzoic acid

tricyclohexylphosphine

Downstream raw materials:

rhodium(carbonyl)4