caesium {bis(η5-1-phenylborole)rhodate}

Base Information

Chemical Name:caesium {bis(η5-1-phenylborole)rhodate}
CAS No.:110726-03-9
Molecular Formula:C₂₀H₁₈B₂Rh*Cs
Molecular Weight:515.796
Hs Code.:

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Chemical Property of caesium {bis(η5-1-phenylborole)rhodate}

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Technology Process of caesium {bis(η5-1-phenylborole)rhodate}

There total 1 articles about caesium {bis(η5-1-phenylborole)rhodate} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: caesium nitrate

: 87883-14-5
μ-(η5-C4H4B(C6H5)){Rh(η5-C4H4B(C6H5))}2

: (η5-cyclopentadienyl)(η5-1-phenylborole)rhodium

: 110726-03-9
caesium {bis(η5-1-phenylborole)rhodate}

Guidance literature:: With C₅H₅Na; In tetrahydrofuran; (N2); Rh2((C4H4B)(C6H5))3 and C5H5Na warmed (20 h, 40°C); solvent removed (vac.); treated with diethyl ether/water; NMe4Br added to aq. phase; (CH3)4NRh((C4H4B)(C6H5))2 filtered off, washed, dried, recrystd. (CH3CN/Et2O or acetone/Et2O); org. phase filtered (Al2O3, 7 % H2O), washed, brought to dryness, sublimed (max. 90°C, 1E-6 bar) to yield (C5H5)Rh((C4H4B)(C6H5)); elem.anal.;
DOI:10.1016/0022-328X(86)80275-3

Reference yield: 86.0%

: cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate

: 110726-03-9
caesium {bis(η5-1-phenylborole)rhodate}

: (C4H4BPh)Rh(μ-η5:η5-C4H4BPh)Ru(cyclopentadienyl)

Guidance literature:: In dichloromethane; (inert atmosphere); stirring mixture of rhodium compd. and ruthenium compd. in CH2Cl2 at room temp. for 12 h; evapn., chromy. (alumina, hexane-CH2Cl2 (7:1)), collecting colored band,evapn., recrystn. (petroleum ether/ethanol), elem. anal.;
DOI:10.1016/j.jorganchem.2006.03.032

Reference yield: 81.0%

: tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate

: 110726-03-9
caesium {bis(η5-1-phenylborole)rhodate}

: (C4H4BPh)Rh(μ-η5:η5-C4H4BPh)Ru(C5Me5)

Guidance literature:: In dichloromethane; (inert atmosphere); stirring mixture of rhodium compd. and ruthenium compd. in CH2Cl2 at room temp. for 12 h; evapn., chromy. (alumina, hexane-CH2Cl2 (7:1)), collecting colored band,evapn., recrystn. (petroleum ether/ethanol), elem. anal.;
DOI:10.1016/j.jorganchem.2006.03.032