oxo bis-(3-hydroxo 1,3-diphenyl triazene-⁽¹⁾) vanadium (IV)

Base Information

• Chemical Name: oxo bis-(3-hydroxo 1,3-diphenyl triazene-⁽¹⁾) vanadium (IV)
• CAS No.: 15130-06-0
• Molecular Formula: C₂₄H₂₀N₆O₃V
• Molecular Weight: 491.403
• Mol file: 15130-06-0.mol

Synonyms:

Chemical Property of oxo bis-(3-hydroxo 1,3-diphenyl triazene-⁽¹⁾) vanadium (IV)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of oxo bis-(3-hydroxo 1,3-diphenyl triazene-⁽¹⁾) vanadium (IV)

There total 2 articles about oxo bis-(3-hydroxo 1,3-diphenyl triazene-⁽¹⁾) vanadium (IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(phenyl)-3-phenyl-3-hydroxytriazene (5756-82-1) → oxo bis-(3-hydroxo 1,3-diphenyl triazene-(1)) vanadium (IV) (15130-06-0)

Guidance literature:

With NH₄ vanadate; In ethanol; reaction of 0.2 g NH4 vanadate in 10 ml H2O with 1.2 g of the triazene in 100 ml ethanol and addition of diluted H2SO4 to pH = 2 - 3;;

Reference yield:

oxovanadium(IV) sulfate + 1-(phenyl)-3-phenyl-3-hydroxytriazene (5756-82-1) → oxo bis-(3-hydroxo 1,3-diphenyl triazene-(1)) vanadium (IV) (15130-06-0)

Guidance literature:

In ethanol; addition of 0.25g VOSO4 in 10 ml H2O to a solution of 0.6 g of the triazene in 60 ml ethanol and cooling down;; crystallization; washing with ethanol and drying in vacuum over CaCl2;;

Reference yield:

oxo bis-(3-hydroxo 1,3-diphenyl triazene-(1)) vanadium (IV) (15130-06-0) → dioxo (3-hydroxo 1,3-diphenyl triazene-(1)) α-picoline vanadium (V) (98783-80-3)

Guidance literature:

In further solvent(s); passing O2 through a solution in α-picoline or heating;;

upstream raw materials:

1-(phenyl)-3-phenyl-3-hydroxytriazene

Downstream raw materials:

dioxo (3-hydroxo 1,3-diphenyl triazene-⁽¹⁾) pyridine vanadium (V)

dioxo (3-hydroxo 1,3-diphenyl triazene-⁽¹⁾) aniline vanadium (V)

dioxo (3-hydroxo 1,3-diphenyl triazene-(1)) α-picoline vanadium (V)