methyl 2,3,4-tri-O-benzyl-6-O-(methyl 4-O-acetyl-3-O-benzyl-2-deoxy-2-fluoro-β-D-mannopyranosyl uronate)-α-D-glucopyranoside

Base Information

• Chemical Name: methyl 2,3,4-tri-O-benzyl-6-O-(methyl 4-O-acetyl-3-O-benzyl-2-deoxy-2-fluoro-β-D-mannopyranosyl uronate)-α-D-glucopyranoside
• CAS No.: 1320281-68-2
• Molecular Formula: C₄₄H₄₉FO₁₂
• Molecular Weight: 788.864
• Mol file: 1320281-68-2.mol

Synonyms:

Chemical Property of methyl 2,3,4-tri-O-benzyl-6-O-(methyl 4-O-acetyl-3-O-benzyl-2-deoxy-2-fluoro-β-D-mannopyranosyl uronate)-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 2,3,4-tri-O-benzyl-6-O-(methyl 4-O-acetyl-3-O-benzyl-2-deoxy-2-fluoro-β-D-mannopyranosyl uronate)-α-D-glucopyranoside

There total 1 articles about methyl 2,3,4-tri-O-benzyl-6-O-(methyl 4-O-acetyl-3-O-benzyl-2-deoxy-2-fluoro-β-D-mannopyranosyl uronate)-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl 2,3,4-tri-O-benzyl-D-glucopyranoside (53008-65-4,641635-63-4) + C29H30O7S (1320281-30-8) + methyl (phenyl 4-O-acetyl-3-O-benzyl-2-deoxy-2-fluoro-1-thio-α-D-mannopyranosyluronate) (1320281-75-1) → methyl 2,3,4-tri-O-benzyl-6-O-(methyl (4-O-acetyl-2,3-di-O-benzyl-β-D-mannopyranosyl)uronate)-α-D-glucopyranoside + methyl 2,3,4-tri-O-benzyl-6-O-(methyl 4-O-acetyl-3-O-benzyl-2-deoxy-2-fluoro-β-D-mannopyranosyl uronate)-α-D-glucopyranoside (1320281-68-2) + methyl 2,3,4-tri-O-benzyl-6-O-(methyl 4-O-acetyl-3-O-benzyl-2-deoxy-2-fluoro-α-D-mannopyranosyl uronate)-α-D-glucopyranoside

Guidance literature:

methyl 2,3,4-tri-O-benzyl-D-glucopyranoside; C₂₉H₃₀O₇S; methyl (phenyl 4-O-acetyl-3-O-benzyl-2-deoxy-2-fluoro-1-thio-α-D-mannopyranosyluronate); In dichloromethane; at 20 ℃; for 0.5h; Molecular sieve; Inert atmosphere;

With N-iodo-succinimide; trifluorormethanesulfonic acid; In dichloromethane; at -40 - 0 ℃; for 3h; optical yield given as %de; stereoselective reaction; Inert atmosphere;

DOI:10.1021/ol2016862

upstream raw materials:

methyl 2,3,4-tri-O-benzyl-D-glucopyranoside

C₂₉H₃₀O₇S

methyl (phenyl 4-O-acetyl-3-O-benzyl-2-deoxy-2-fluoro-1-thio-α-D-mannopyranosyluronate)