C₄₄H₇₅NO₅S₂Si₂

Base Information

Chemical Name:C₄₄H₇₅NO₅S₂Si₂
CAS No.:1351657-19-6
Molecular Formula:C₄₄H₇₅NO₅S₂Si₂
Molecular Weight:818.386
Hs Code.:

C<sub>44</sub>H<sub>75</sub>NO<sub>5</sub>S<sub>2</sub>Si<sub>2</sub>

Synonyms:

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Chemical Property of C₄₄H₇₅NO₅S₂Si₂

Chemical Property:

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Technology Process of C₄₄H₇₅NO₅S₂Si₂

There total 30 articles about C₄₄H₇₅NO₅S₂Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1351657-18-5
C₃₈H₆₁NO₅S₂Si

: 79271-56-0
triethylsilyl trifluoromethyl sulfonate

: 1351657-19-6
C₄₄H₇₅NO₅S₂Si₂

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane;
DOI:10.1016/j.tetlet.2011.10.073

Reference yield:

: 80657-88-1
(2R,4R)-2-Methyl-4-((4S,5R)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-pentan-1-ol

: 1351657-19-6
C₄₄H₇₅NO₅S₂Si₂

Guidance literature:: Multi-step reaction with 25 steps

1: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane

2: sodium hydride / tetrahydrofuran

3: diisobutylaluminium hydride / tetrahydrofuran

4: titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate / dichloromethane

5: pyridine; tributylphosphine

6: dichloromethane

7: tetra-(n-butyl)ammonium iodide; sodium hydride / N,N-dimethyl-formamide

8: sodium periodate / methanol; water

9: 2,6-dimethylpyridine; trifluoroacetic anhydride / acetonitrile

10: sodium hydride / tetrahydrofuran

11: aluminum oxide; 20 % Pd(OH)2/C; hydrogen / ethanol

12: pyridinium p-toluenesulfonate / 1,2-dichloro-ethane

13: lithium diisopropyl amide / tetrahydrofuran

14: lithium aluminium tetrahydride / tetrahydrofuran

15: 1H-imidazole / dichloromethane

16: tetra-(n-butyl)ammonium iodide; potassium hydride / tetrahydrofuran

17: tetrabutyl ammonium fluoride / tetrahydrofuran

18: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran

19: hydrogenchloride / methanol

20: 2,6-dimethylpyridine / dichloromethane

21: pyridine; pyridine hydrogenfluoride / tetrahydrofuran

22: Dess-Martin periodane / dichloromethane

23: tetrahydrofuran / 0 °C

24: 3-chloro-benzenecarboperoxoic acid / dichloromethane

25: 2,6-dimethylpyridine / dichloromethane

With pyridine; 1H-imidazole; 2,6-dimethylpyridine; titanium(IV) isopropylate; hydrogenchloride; tert.-butylhydroperoxide; aluminum oxide; sodium periodate; lithium aluminium tetrahydride; oxalyl dichloride; diethyl (2S,3S)-tartrate; tributylphosphine; di-isopropyl azodicarboxylate; 20 % Pd(OH)2/C; tetrabutyl ammonium fluoride; hydrogen; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; potassium hydride; sodium hydride; diisobutylaluminium hydride; Dess-Martin periodane; pyridine hydrogenfluoride; dimethyl sulfoxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; trifluoroacetic anhydride; lithium diisopropyl amide; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; 1,2-dichloro-ethane; N,N-dimethyl-formamide; acetonitrile; 1: Swern oxidation / 2: Horner-Emmons olefination / 4: Katsuki-Sharpless epoxidation / 9: Pummerer rearrangement / 10: Horner-Emmons olefination / 22: Dess-Martin oxidation;
DOI:10.1016/j.tetlet.2011.10.073

Reference yield:

: C₁₃H₂₄O₃

: 1351657-19-6
C₄₄H₇₅NO₅S₂Si₂

Guidance literature:: Multi-step reaction with 24 steps

1: sodium hydride / tetrahydrofuran

2: diisobutylaluminium hydride / tetrahydrofuran

3: titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate / dichloromethane

4: pyridine; tributylphosphine

5: dichloromethane

6: tetra-(n-butyl)ammonium iodide; sodium hydride / N,N-dimethyl-formamide

7: sodium periodate / methanol; water

8: 2,6-dimethylpyridine; trifluoroacetic anhydride / acetonitrile

9: sodium hydride / tetrahydrofuran

10: aluminum oxide; 20 % Pd(OH)2/C; hydrogen / ethanol

11: pyridinium p-toluenesulfonate / 1,2-dichloro-ethane

12: lithium diisopropyl amide / tetrahydrofuran

13: lithium aluminium tetrahydride / tetrahydrofuran

14: 1H-imidazole / dichloromethane

15: tetra-(n-butyl)ammonium iodide; potassium hydride / tetrahydrofuran

16: tetrabutyl ammonium fluoride / tetrahydrofuran

17: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran

18: hydrogenchloride / methanol

19: 2,6-dimethylpyridine / dichloromethane

20: pyridine; pyridine hydrogenfluoride / tetrahydrofuran

21: Dess-Martin periodane / dichloromethane

22: tetrahydrofuran / 0 °C

23: 3-chloro-benzenecarboperoxoic acid / dichloromethane

24: 2,6-dimethylpyridine / dichloromethane

With pyridine; 1H-imidazole; 2,6-dimethylpyridine; titanium(IV) isopropylate; hydrogenchloride; tert.-butylhydroperoxide; aluminum oxide; sodium periodate; lithium aluminium tetrahydride; diethyl (2S,3S)-tartrate; tributylphosphine; di-isopropyl azodicarboxylate; 20 % Pd(OH)2/C; tetrabutyl ammonium fluoride; hydrogen; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; potassium hydride; sodium hydride; diisobutylaluminium hydride; Dess-Martin periodane; pyridine hydrogenfluoride; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; trifluoroacetic anhydride; lithium diisopropyl amide; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; 1,2-dichloro-ethane; N,N-dimethyl-formamide; acetonitrile; 1: Horner-Emmons olefination / 3: Katsuki-Sharpless epoxidation / 8: Pummerer rearrangement / 9: Horner-Emmons olefination / 21: Dess-Martin oxidation;
DOI:10.1016/j.tetlet.2011.10.073