Technology Process of C27H23ClO7
There total 14 articles about C27H23ClO7 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C27H25ClO8;
With
methanesulfonyl chloride; N-ethyl-N,N-diisopropylamine;
In
dichloromethane;
at 0 ℃;
Inert atmosphere;
With
potassium carbonate;
In
tetrahydrofuran; methanol;
at 0 ℃;
for 1h;
Inert atmosphere;
DOI:10.1002/chem.201402254
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / 20 h / 65 °C / Inert atmosphere
2.1: sodium acetate; acetic acid / 12 h / 80 °C / Inert atmosphere
3.1: hydrogenchloride; water / methanol; tetrahydrofuran / 16 h / 50 °C
4.1: toluene-4-sulfonic acid / acetone / 0.33 h / Inert atmosphere
4.2: 0.33 h
5.1: triethylamine; dmap / dichloromethane / 2 h / 0 °C / Inert atmosphere
6.1: hydrogenchloride; water / methanol; tetrahydrofuran / 16 h / 50 °C
7.1: methanesulfonyl chloride; N-ethyl-N,N-diisopropylamine / dichloromethane / 0 °C / Inert atmosphere
7.2: 1 h / 0 °C / Inert atmosphere
With
hydrogenchloride; dmap; water; sodium acetate; toluene-4-sulfonic acid; acetic acid; methanesulfonyl chloride; triethylamine; N-ethyl-N,N-diisopropylamine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
In
tetrahydrofuran; methanol; dichloromethane; ethyl acetate; acetone;
DOI:10.1002/chem.201402254
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: hydrogenchloride; water / methanol; tetrahydrofuran / 16 h / 50 °C
2.1: methanesulfonyl chloride; N-ethyl-N,N-diisopropylamine / dichloromethane / 0 °C / Inert atmosphere
2.2: 1 h / 0 °C / Inert atmosphere
With
hydrogenchloride; water; methanesulfonyl chloride; N-ethyl-N,N-diisopropylamine;
In
tetrahydrofuran; methanol; dichloromethane;
DOI:10.1002/chem.201402254
