(3-Amino-2,2,6,6-tetramethyl-1-oxyl-4-piperidyl)ammonium benzoate

Base Information

• Chemical Name: (3-Amino-2,2,6,6-tetramethyl-1-oxyl-4-piperidyl)ammonium benzoate
• CAS No.: 127479-41-8
• Molecular Formula: C₇H₆O₂*C₉H₂₀N₃O
• Molecular Weight: 308.401
• Mol file: 127479-41-8.mol

Synonyms:

Chemical Property of (3-Amino-2,2,6,6-tetramethyl-1-oxyl-4-piperidyl)ammonium benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (3-Amino-2,2,6,6-tetramethyl-1-oxyl-4-piperidyl)ammonium benzoate

There total 6 articles about (3-Amino-2,2,6,6-tetramethyl-1-oxyl-4-piperidyl)ammonium benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,4-Diamino-2,2,6,6-tetramethylpiperidine (127479-34-9) → (3-Amino-2,2,6,6-tetramethyl-1-oxyl-4-piperidyl)ammonium benzoate (127479-41-8)

Guidance literature:

Multi-step reaction with 4 steps

1: 80 percent / dimethylformamide / 3 h / 20 °C

2: 90 percent / p-nitroperbenzoic acid / ethyl acetate / 2 h / 20 °C

3: 73 percent / KOH

4: diethyl ether / 92 h

With 4-nitroperbenzoic acid; potassium hydroxide; In diethyl ether; ethyl acetate; N,N-dimethyl-formamide;

DOI:10.1007/BF00957793

Reference yield:

2,2,6,6-tetramethyl-3-chloro-4-hydroxyiminopiperidine-1-oxide (85540-95-0) → (3-Amino-2,2,6,6-tetramethyl-1-oxyl-4-piperidyl)ammonium benzoate (127479-41-8)

Guidance literature:

Multi-step reaction with 6 steps

1: 87 percent / NH₃

2: 68 percent / Na / butan-1-ol / 0.5 h / 90 - 100 °C

3: 80 percent / dimethylformamide / 3 h / 20 °C

4: 90 percent / p-nitroperbenzoic acid / ethyl acetate / 2 h / 20 °C

5: 73 percent / KOH

6: diethyl ether / 92 h

With 4-nitroperbenzoic acid; potassium hydroxide; ammonia; sodium; In diethyl ether; ethyl acetate; N,N-dimethyl-formamide; butan-1-ol;

DOI:10.1007/BF00957793

Reference yield:

3-Amino-4-hydroxyimino-2,2,6,6-tetramethyl-piperidine-1-oxyl (127479-33-8) → (3-Amino-2,2,6,6-tetramethyl-1-oxyl-4-piperidyl)ammonium benzoate (127479-41-8)

Guidance literature:

Multi-step reaction with 5 steps

1: 68 percent / Na / butan-1-ol / 0.5 h / 90 - 100 °C

2: 80 percent / dimethylformamide / 3 h / 20 °C

3: 90 percent / p-nitroperbenzoic acid / ethyl acetate / 2 h / 20 °C

4: 73 percent / KOH

5: diethyl ether / 92 h

With 4-nitroperbenzoic acid; potassium hydroxide; sodium; In diethyl ether; ethyl acetate; N,N-dimethyl-formamide; butan-1-ol;

DOI:10.1007/BF00957793

upstream raw materials:

3,4-Diamino-2,2,6,6-tetramethylpiperidine-1-oxyl

benzoic acid

3,4-Diamino-2,2,6,6-tetramethylpiperidine

2,2,6,6-tetramethyl-3-chloro-4-hydroxyiminopiperidine-1-oxide