[(C₆H₅)3P]2N⁽¹⁺⁾*[(C₅H₄NOS)3Mn]^(1-)=[(C₆H₅)3P]2N[(C₅H₄NOS)3Mn]

Base Information

• Chemical Name: [(C₆H₅)3P]2N⁽¹⁺⁾*[(C₅H₄NOS)3Mn]^(1-)=[(C₆H₅)3P]2N[(C₅H₄NOS)3Mn]
• CAS No.: 444303-24-6
• Molecular Formula: C₁₅H₁₂MnN₃O₃S₃*C₃₆H₃₀NP₂
• Molecular Weight: 972.003
• Mol file: 444303-24-6.mol

Synonyms:

Chemical Property of [(C₆H₅)3P]2N⁽¹⁺⁾*[(C₅H₄NOS)3Mn]^(1-)=[(C₆H₅)3P]2N[(C₅H₄NOS)3Mn]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(C₆H₅)3P]2N⁽¹⁺⁾*[(C₅H₄NOS)3Mn]^(1-)=[(C₆H₅)3P]2N[(C₅H₄NOS)3Mn]

There total 2 articles about [(C₆H₅)3P]2N⁽¹⁺⁾*[(C₅H₄NOS)3Mn]^(1-)=[(C₆H₅)3P]2N[(C₅H₄NOS)3Mn] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

bis(triphenylphosphineiminium) pentacarbonylmanganate(1-) (52542-59-3,192520-17-5) + 2,2'-dipyridyl disulfide bis-N-oxide (3696-28-4) → [(C6H5)3P]2N(1+)*[(C5H4NOS)3Mn](1-)=[(C6H5)3P]2N[(C5H4NOS)3Mn] (444303-24-6)

Guidance literature:

In tetrahydrofuran; (N2); a soln. of disulfide and Mn carbonyl salt stirred at ambient temp.for 5 min; the mixt. then stirred under air-O2 overnight at room temp.; the soln. removed via cannula; ppt. washed with THF; solid extd. with MeCN, ether slowly added to ppt. the product; elem. anal.; the crystals suitable for X-ray crystallografy obtained by vapor diffusion of ether into concd. MeCN soln. of complex;

DOI:10.1016/S0020-1693(02)00733-8

Reference yield:

1-hydroxy-2(1H)-pyridinethione (1121-30-8) + bis(triphenylphosphineiminium) pentacarbonylmanganate(1-) (52542-59-3,192520-17-5) → [(C6H5)3P]2N(1+)*[(C5H4NOS)3Mn](1-)=[(C6H5)3P]2N[(C5H4NOS)3Mn] (444303-24-6)

Guidance literature:

In tetrahydrofuran; obtained by stirring overnight a mixt. of pyridinethione and Mn carbonylsalt (2:1) in THF at ambient temp.;

DOI:10.1016/S0020-1693(02)00733-8

upstream raw materials:

bis(triphenylphosphineiminium) pentacarbonylmanganate^(1-)

2,2'-dipyridyl disulfide bis-N-oxide

1-hydroxy-2(1H)-pyridinethione