[(η5-C5H5)Ti(OC6HPh4-2,3,5,6)Me2]

Base Information

Chemical Name:[(η5-C5H5)Ti(OC6HPh4-2,3,5,6)Me2]
CAS No.:695229-51-7
Molecular Formula:C₃₇H₃₂OTi
Molecular Weight:540.54
Hs Code.:

Synonyms:

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Chemical Property of [(η5-C5H5)Ti(OC6HPh4-2,3,5,6)Me2]

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Technology Process of [(η5-C5H5)Ti(OC6HPh4-2,3,5,6)Me2]

There total 1 articles about [(η5-C5H5)Ti(OC6HPh4-2,3,5,6)Me2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 1270-98-0
cyclopentadienyl titanium(IV) trichloride

: 913-63-3
2,3,5,6-tetraphenylphenol

: 917-54-4
methyllithium

: 695229-51-7
[(η5-C5H5)Ti(OC6HPh4-2,3,5,6)Me2]

Guidance literature:: In diethyl ether; byproducts: LiCl, CH4; (N2); standard Schlenk technique; soln. of LiMe (3 equiv.) in Et2O was added via syringe to soln. of Ti complex in Et2O at -78°C; mixt. was stirred for 4 h; phenol was added with stirring; mixt. was slowly warmed to room temp.; stirred overnight; solvent removed (vac.); C6H6 added; filtered through Celite; filtrate evacuated; elem. anal.;
DOI:10.1021/om0341404

Reference yield: 99.0%

: [(η(5)-C5H5)Ti(OC6HPh4-2,3,5,6)Cl2]

: 695229-51-7
[(η5-C5H5)Ti(OC6HPh4-2,3,5,6)Me2]

: 874291-10-8
[(η5-C5H5)Ti(OC6HPh4-2,3,5,6)MeCl]

Guidance literature:: In benzene; heating a soln. of complexes in benzene;
DOI:10.1021/om0507272

Reference yield:

: 695229-51-7
[(η5-C5H5)Ti(OC6HPh4-2,3,5,6)Me2]

: 1109-15-5
tris(pentafluorophenyl)borate

: 874291-15-3,695229-58-4
[(η5-C5H5)Ti(OC6HPh4-2,3,5,6)Me][MeB(C6F5)3]

Guidance literature:: In ⁽²⁾H₈-toluene; (N2); standard Schlenk technique; NMR tube was charged with Ti complex, B(C6F5)3 and C7D8; quickly placed in ice/acetone bath; NMR monitoring; not isolated;
DOI:10.1021/om0341404