Tricyclo[4.2.1.02,5]nonane,exo-

Base Information

• Chemical Name: Tricyclo[4.2.1.02,5]nonane,exo-
• CAS No.: 16526-27-5
• Molecular Formula: C₉H₁₄
• Molecular Weight: 122.21
• Mol file: 16526-27-5.mol

Synonyms:Tricyclo[4.2.1.02,5]nonane,exo- (8CI); exo-Tricyclo[4.2.1.02,5]nonane

Chemical Property of Tricyclo[4.2.1.02,5]nonane,exo-

Chemical Property:

• Vapor Pressure: 2.8mmHg at 25°C
• Boiling Point: 162.6°Cat760mmHg
• Flash Point: 32.2°C
• PSA: 0.00000
• Density: 1.004g/cm³
• LogP: 2.44250

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Tricyclo[4.2.1.02,5]nonane,exo-

There total 6 articles about Tricyclo[4.2.1.02,5]nonane,exo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

3-ethyl-3-alumatricyclo<5.2.1.02,5>decane → exo-tricyclo<4.2.1.02,5>nonane (16526-27-5)

Guidance literature:

With palladium(II) acetylacetonate; triphenylphosphine; 3-chloroprop-1-ene; In tetrahydrofuran; at 20 ℃; for 10h;

DOI:10.1007/BF00695821

Reference yield: 52.0%

exo,cis-1,2-bis(iodomethyl)bicyclo<2.2.1>heptane (85807-80-3) → exo-tricyclo<4.2.1.02,5>nonane (16526-27-5)

Guidance literature:

With tert.-butyl lithium; In diethyl ether; pentane; at -23 ℃; for 0.5h;

DOI:10.1021/jo00186a004

Reference yield:

exo-Tricyclo<4.2.1.O2,5>nonen-(3) (16529-76-3) → exo-tricyclo<4.2.1.02,5>nonane (16526-27-5)

Guidance literature:

With hydrogen; platinum(IV) oxide; In diethyl ether;

DOI:10.1021/jo01270a001

upstream raw materials:

exo-Tricyclo<4.2.1.O^2,5>nonen-(7)

exo-Tricyclo<4.2.1.O^2,5>nonen-(3)

exo,cis-1,2-bis(iodomethyl)bicyclo<2.2.1>heptane

Refernces

• 1、 Bailey, William F.,Gagnier, Paul R.,Patricia, Jeffrey J.. "Reactions of tert-Butyllithium with α,ω-Dihaloalkanes. Evidence for Single-Electron-Transfer-Mediated Metal-Halogen Interchange Involving Alkyl Radical-Halide Ion Adducts". . p. 2098 - 2107. Retrieved 2007/10/02.