(CH₃(CH₂)3)4N⁽¹⁺⁾*W(CO)3(C₅H₅)^(1-)=(CH₃(CH₂)3)4N(W(CO)3(C₅H₅))

Base Information

• Chemical Name: (CH₃(CH₂)3)4N⁽¹⁺⁾*W(CO)3(C₅H₅)^(1-)=(CH₃(CH₂)3)4N(W(CO)3(C₅H₅))
• CAS No.: 68914-56-7
• Molecular Formula: C₈H₅O₃W*C₁₆H₃₆N
• Molecular Weight: 575.444
• Mol file: 68914-56-7.mol

Synonyms:

Chemical Property of (CH₃(CH₂)3)4N⁽¹⁺⁾*W(CO)3(C₅H₅)^(1-)=(CH₃(CH₂)3)4N(W(CO)3(C₅H₅))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (CH₃(CH₂)3)4N⁽¹⁺⁾*W(CO)3(C₅H₅)^(1-)=(CH₃(CH₂)3)4N(W(CO)3(C₅H₅))

There total 1 articles about (CH₃(CH₂)3)4N⁽¹⁺⁾*W(CO)3(C₅H₅)^(1-)=(CH₃(CH₂)3)4N(W(CO)3(C₅H₅)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[tetra-n-butylammonium][tris(pentafluorophenyl)((tricarbonyl)(cyclopentadienyl)W)aurate] → (CH3(CH2)3)4N(1+)*W(CO)3(C5H5)(1-)=(CH3(CH2)3)4N(W(CO)3(C5H5)) (68914-56-7) + [Au(C6F5)3(P(C6H5)3)] (27681-40-9)

Guidance literature:

With PPh₃; In dichloromethane; equimolar mixture, room temp.; mixture sepg. by evapn. to dryness, extn. with diethyl ether;

DOI:10.1039/DT9810000366

Reference yield: 75.0%

{Tl(C6F5)3(1,4-dioxane)} + (CH3(CH2)3)4N(1+)*W(CO)3(C5H5)(1-)=(CH3(CH2)3)4N(W(CO)3(C5H5)) (68914-56-7) → [NBu4][Tl(C6F5)3(W(η-C5H5)(CO)3)]

Guidance literature:

In dichloromethane; under N2, to suspn. of Tl complex in CH2Cl2 added W complex, stirred for 15 min at room temp.; concd., hexane added; elem. anal.;

DOI:10.1039/DT9830001127

Reference yield: 40.0%

pentafluorophenyl(tetrahydrothiophene)gold(I) + (CH3(CH2)3)4N(1+)*W(CO)3(C5H5)(1-)=(CH3(CH2)3)4N(W(CO)3(C5H5)) (68914-56-7) → [Bu4N][Au(C6F5)2] + [tetra-n-butylammonium][bis((tricarbonyl)(cyclopentadienyl)W)aurate]

Guidance literature:

In dichloromethane; stirring 10 min at room temp.; evapg. to dryness; 5x washing with diethyl ether; filtering; evapg. ether from filtrate;

DOI:10.1039/DT9810000366