[Cr(CO)5(2-(azidomethyl)phenyl isocyanide)]

Base Information

Chemical Name:[Cr(CO)5(2-(azidomethyl)phenyl isocyanide)]
CAS No.:690229-25-5
Molecular Formula:C₁₃H₆CrN₄O₅
Molecular Weight:350.21
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Cr(CO)5(2-(azidomethyl)phenyl isocyanide)]

Chemical Property:

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Technology Process of [Cr(CO)5(2-(azidomethyl)phenyl isocyanide)]

There total 1 articles about [Cr(CO)5(2-(azidomethyl)phenyl isocyanide)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.7%

: 14780-98-4
tetraethylammonium pentacarbonyliodochromate⁽⁰⁾

: 496963-67-8
1-(azidomethyl)-2-isocyanobenzene

: 690229-25-5
[Cr(CO)5(2-(azidomethyl)phenyl isocyanide)]

Guidance literature:: With silver tetrafluoroborate; In acetone; byproducts: AgI, Et4NBF4; under N2; acetone soln. of AgBF4 (0.95 equiv.) added dropwise (20 min) to suspn. of Cr complex in acetone at 0°C; quickly filtered; filtrate treated dropwise with soln. of ligand (0.9 equiv.) in acetone; stirred for 20 min; warmed to room temp.; evapd. to dryness; column chromd. (silica gel, Et2O-n-hexane); green band collected; taken to dryness under reduced pressure; oil rapidly solidified; dried under vac.; elem. anal.;
DOI:10.1016/S0020-1693(03)00407-9

Reference yield:

: 690229-25-5
[Cr(CO)5(2-(azidomethyl)phenyl isocyanide)]

: 603-35-0
triphenylphosphine

: 690229-32-4
[Cr(CO)5(CNC₆H₄-2-CH₂N=PPh₃)]

Guidance literature:: In dichloromethane; byproducts: N2, Ph3PO; under N2; PPh3 (1 equiv.) added to soln. of Cr complex in CH2Cl2; stirred at room temp. overnight; monitored by IR spectra; taken to dryness; dried under vac.; elem. anal.; final Cr complex coud not be sepd. from Ph3PO;
DOI:10.1016/S0020-1693(03)00407-9