Propanal,2-[2-(2,4-dinitrophenyl)hydrazinylidene]-, 2-(2,4-dinitrophenyl)hydrazone

Base Information

• Chemical Name: Propanal,2-[2-(2,4-dinitrophenyl)hydrazinylidene]-, 2-(2,4-dinitrophenyl)hydrazone
• CAS No.: 1107-69-3
• Molecular Formula: C15H12 N8 O8
• Molecular Weight: 432.309
• Mol file: 1107-69-3.mol

Synonyms:Propanal,2-[(2,4-dinitrophenyl)hydrazono]-, (2,4-dinitrophenyl)hydrazone (9CI);Pyruvaldehyde, bis[(2,4-dinitrophenyl)hydrazone] (6CI,7CI,8CI);1,2-Propanedione bis(2,4-dinitrophenylhydrazone); Methylglyoxalbis[(2,4-dinitrophenyl)hydrazone]

Chemical Property of Propanal,2-[2-(2,4-dinitrophenyl)hydrazinylidene]-, 2-(2,4-dinitrophenyl)hydrazone

Chemical Property:

• XLogP3: 4.3
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 5
• Exact Mass: 432.07780937
• Heavy Atom Count: 31
• Complexity: 752

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=NNC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-])C=NNC2=C(C=C(C=C2)[N+](=O)[O-])[N+](=O)[O-]
• Isomeric SMILES: C/C(=N\NC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-])/C=N/NC2=C(C=C(C=C2)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of Propanal,2-[2-(2,4-dinitrophenyl)hydrazinylidene]-, 2-(2,4-dinitrophenyl)hydrazone

There total 23 articles about Propanal,2-[2-(2,4-dinitrophenyl)hydrazinylidene]-, 2-(2,4-dinitrophenyl)hydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

(2,4-dinitro-phenyl)-hydrazine (119-26-6) + 2,4,6-triacetyl-1,3,5-trioxane (225793-59-9) → pyruvaldehyde bis-(2,4-dinitro-phenylhydrazone) (1107-69-3)

Guidance literature:

With hydrogenchloride; In ethanol; at 60 ℃; for 0.25h;

DOI:10.1007/BF02641556

Reference yield: 60.0%

N-(2,4-dinitrophenyl)-N'-isopropylidene-hydrazine (1567-89-1) → pyruvaldehyde bis-(2,4-dinitro-phenylhydrazone) (1107-69-3)

Guidance literature:

With mercury(II) diacetate; In acetic acid; 1.) 2.5 h, room temperature, 2.) 3.5 h, 64-68 deg C;

Reference yield: 45.0%

α-acetyloxyacrolein (69864-54-6) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → pyruvaldehyde bis-(2,4-dinitro-phenylhydrazone) (1107-69-3)

Guidance literature:

With hydrogenchloride; In ethanol; at 60 ℃; for 0.25h;

DOI:10.1007/BF00949461

upstream raw materials:

quinoline

2.4-Dinitro-phenylhydrazon des Chloracetons

DL-glycerolaldehyde-2,4-dinitro-phenylhydrazone

dihydroxyacetone phosphate

Refernces

• 1、 Keiko, N. A.,Musorina, T. N.,Frolov, Yu. L.,Shulunova, A. M.,Chuvashov, Yu. A.,Voronkov, M. G.. "COMPARATIVE REACTIVITY OF α-ACETOXYACROLEIN AND α-ETHOXYACROLEIN". . p. 1634 - 1636. Retrieved 2007/10/02.
• 2、 Treindl, Ludovit,Melichercik, Milan. "KINETICS AND MECHANISM OF THE REDOX REACTION OF THALLIC SULPHATE WITH ACROLEINE". . p. 1173 - 1181. Retrieved 2007/10/02.