cis-[(2,2':6',2''-terpyridine)OsCl2(η2-(C,N)-PhCH=N=CH[C6H4NMe2])]PF6

Base Information

• Chemical Name: cis-[(2,2':6',2''-terpyridine)OsCl2(η2-(C,N)-PhCH=N=CH[C6H4NMe2])]PF6
• CAS No.: 690258-88-9
• Molecular Formula: C₃₁H₂₈Cl₂N₅Os*F₆P
• Molecular Weight: 876.667
• Mol file: 690258-88-9.mol

Synonyms:

Chemical Property of cis-[(2,2':6',2''-terpyridine)OsCl2(η2-(C,N)-PhCH=N=CH[C6H4NMe2])]PF6

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[(2,2':6',2''-terpyridine)OsCl2(η2-(C,N)-PhCH=N=CH[C6H4NMe2])]PF6

There total 1 articles about cis-[(2,2':6',2''-terpyridine)OsCl2(η2-(C,N)-PhCH=N=CH[C6H4NMe2])]PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

cis-[Os(VI)(2,2':6',2''-terpyridine)(Cl)2(N)](PF6) (127571-48-6,159248-17-6) + 4-(N,N-dimethylamino)stilbene (838-95-9,1145-73-9,14301-11-2) → cis-[(2,2':6',2''-terpyridine)OsCl2(η2-(C,N)-PhCH=N=CH[C6H4NMe2])]PF6 (690258-88-9)

Guidance literature:

In acetonitrile; soln. of Os-complex and ligand in MeCN was added into flask, allowed to stand at room temp. for 9 h under N2 or Ar; MeCN was evapd. on rotary evaporator, layered with ether, allowed to stand overnight at -20°C, filtered, washed with Et2O, dried in air;

DOI:10.1021/om034404m

upstream raw materials:

cis-[Os(VI)(2,2':6',2''-terpyridine)(Cl)2(N)](PF₆)

4-(N,N-dimethylamino)stilbene

Refernces