diphenylphosphino-2-bis(m-trifluoromethylphenyl)phosphinoethanetetracarbonylmolybdenum⁽⁰⁾

Base Information

• Chemical Name: diphenylphosphino-2-bis(m-trifluoromethylphenyl)phosphinoethanetetracarbonylmolybdenum⁽⁰⁾
• CAS No.: 106005-90-7
• Molecular Formula: C₃₂H₂₂F₆MoO₄P₂
• Molecular Weight: 742.402
• Mol file: 106005-90-7.mol

Synonyms:

Chemical Property of diphenylphosphino-2-bis(m-trifluoromethylphenyl)phosphinoethanetetracarbonylmolybdenum⁽⁰⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diphenylphosphino-2-bis(m-trifluoromethylphenyl)phosphinoethanetetracarbonylmolybdenum⁽⁰⁾

There total 1 articles about diphenylphosphino-2-bis(m-trifluoromethylphenyl)phosphinoethanetetracarbonylmolybdenum⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-diphenylphosphino-2-m-bis(trifluoromethylphenyl)phosphinoethane (94940-46-2) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → diphenylphosphino-2-bis(m-trifluoromethylphenyl)phosphinoethanetetracarbonylmolybdenum(0) (106005-90-7)

Guidance literature:

In methyl cyclohexane; under N2 atm., Schlenk tube techniques; reflux of mixt. of Cr(CO)6 and P compd. in methylcyclohexane; removal of solvent in vac.; chromy. (silica, chloroform); recrystn. from chloroform/hexane; elem. anal.;

DOI:10.1016/0022-328X(86)80224-8

Reference yield:

diphenylphosphino-2-bis(m-trifluoromethylphenyl)phosphinoethanetetracarbonylmolybdenum(0) (106005-90-7) → diphenylphosphino-2-bis(m-trifluoromethylphenyl)phosphinoethanetricarbonylpyridinomolybdenum(0)

Guidance literature:

With pyridine; In not given; under N2 atm., Schlenk tube techniques; refluxing of Mo-complex with anexcess of pyridine in methylcyclohexane for ca 40h; elem. anal.;

DOI:10.1016/0022-328X(86)80224-8

upstream raw materials:

1-diphenylphosphino-2-m-bis(trifluoromethylphenyl)phosphinoethane

molybdenum hexacarbonyl