Cp*Ir(PPh₂Py)Cl₂

Base Information

• Chemical Name: Cp*Ir(PPh₂Py)Cl₂
• CAS No.: 929882-72-4
• Molecular Formula: C₂₇H₂₉Cl₂IrNP
• Molecular Weight: 661.634
• Mol file: 929882-72-4.mol

Synonyms:

Chemical Property of Cp*Ir(PPh₂Py)Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Cp*Ir(PPh₂Py)Cl₂

There total 1 articles about Cp*Ir(PPh₂Py)Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] (12354-84-6,12354-85-7) + 2-(diphenylphosphino)pyridine (37943-90-1) → Cp*Ir(PPh2Py)Cl2 (929882-72-4)

Guidance literature:

In tetrahydrofuran; (under Ar, Schlenk); Ir-complex and ligand mixed with THF, stirred for 2h; filtered, washed with ether;

DOI:10.1039/b815890h

Reference yield: 77.0%

Cp*Ir(PPh2Py)Cl2 (929882-72-4) + lithium triethylborohydride (22560-16-3) → Cp*Ir(PPh2Py)H2 (1148179-47-8)

Guidance literature:

In tetrahydrofuran; (under Ar, Schlenk); LiB-compound in THF added to suspn. of Ir-complex in THF, stirred for 3 h at room temp.; alumina column chromy. with toluene; elem. anal.;

DOI:10.1039/b815890h

upstream raw materials:

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

2-(diphenylphosphino)pyridine

Downstream raw materials:

Cp*Ir(PPh₂Py)H₂