C₅(CH₃)5IrH(P(CH₃)3)CH₂C₆H₂(CH₃)2SiHC₆H₂(CH₃)3⁽¹⁺⁾*OSO₂CF₃^(1-)=[C₅(CH₃)5IrH(P(CH₃)3)CH₂C₆H₂(CH₃)2SiHC₆H₂(CH₃)3]OSO₂CF₃

Base Information

• Chemical Name: C₅(CH₃)5IrH(P(CH₃)3)CH₂C₆H₂(CH₃)2SiHC₆H₂(CH₃)3⁽¹⁺⁾*OSO₂CF₃^(1-)=[C₅(CH₃)5IrH(P(CH₃)3)CH₂C₆H₂(CH₃)2SiHC₆H₂(CH₃)3]OSO₂CF₃
• CAS No.: 261731-57-1
• Molecular Formula: CF₃O₃S*C₃₁H₄₇IrPSi
• Molecular Weight: 820.064
• Mol file: 261731-57-1.mol

Synonyms:

Chemical Property of C₅(CH₃)5IrH(P(CH₃)3)CH₂C₆H₂(CH₃)2SiHC₆H₂(CH₃)3⁽¹⁺⁾*OSO₂CF₃^(1-)=[C₅(CH₃)5IrH(P(CH₃)3)CH₂C₆H₂(CH₃)2SiHC₆H₂(CH₃)3]OSO₂CF₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅(CH₃)5IrH(P(CH₃)3)CH₂C₆H₂(CH₃)2SiHC₆H₂(CH₃)3⁽¹⁺⁾*OSO₂CF₃^(1-)=[C₅(CH₃)5IrH(P(CH₃)3)CH₂C₆H₂(CH₃)2SiHC₆H₂(CH₃)3]OSO₂CF₃

There total 1 articles about C₅(CH₃)5IrH(P(CH₃)3)CH₂C₆H₂(CH₃)2SiHC₆H₂(CH₃)3⁽¹⁺⁾*OSO₂CF₃^(1-)=[C₅(CH₃)5IrH(P(CH₃)3)CH₂C₆H₂(CH₃)2SiHC₆H₂(CH₃)3]OSO₂CF₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(η(5)-C5Me5)(PMe3)Ir(Me)(OTf) + bis(2,4,6-trimethyphenyl)silane (99798-82-0) → C5(CH3)5IrH(P(CH3)3)CH2C6H2(CH3)2SiHC6H2(CH3)3(1+)*OSO2CF3(1-)=[C5(CH3)5IrH(P(CH3)3)CH2C6H2(CH3)2SiHC6H2(CH3)3]OSO2CF3 (261731-57-1)

Guidance literature:

In dichloromethane-d2; byproducts: CH4; (N2); addn of a soln. of iridium complex in CD2Cl2 to silane; not isolated, detected by NMR;

DOI:10.1021/om020191+

Reference yield:

C5(CH3)5IrH(P(CH3)3)CH2C6H2(CH3)2SiHC6H2(CH3)3(1+)*OSO2CF3(1-)=[C5(CH3)5IrH(P(CH3)3)CH2C6H2(CH3)2SiHC6H2(CH3)3]OSO2CF3 (261731-57-1) → [(C5(CH3)5)(P(CH3)3)Ir(H)Si(C6H2(CH3)3)2](1+)*OSO2CF3(1-)=[(C5(CH3)5)(P(CH3)3)Ir(H)Si(C6H2(CH3)3)2]OSO2CF3 (261731-59-3)

Guidance literature:

In further solvent(s); (N2); react. in ClCD2CD2Cl at temp. from 290 to 320 K; Kinetics;

DOI:10.1021/om020191+

upstream raw materials:

bis(2,4,6-trimethyphenyl)silane

Downstream raw materials:

[(C₅(CH₃)5)(P(CH₃)3)Ir(H)Si(C₆H₂(CH₃)3)2]⁽¹⁺⁾*OSO₂CF₃^(1-)=[(C₅(CH₃)5)(P(CH₃)3)Ir(H)Si(C₆H₂(CH₃)3)2]OSO₂CF₃