4-[(4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4,5-dihydro-furan-2-yl]-4-hydroxy-cyclohexa-2,5-dienone

Base Information

Chemical Name:4-[(4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4,5-dihydro-furan-2-yl]-4-hydroxy-cyclohexa-2,5-dienone
CAS No.:174865-51-1
Molecular Formula:C₂₃H₄₀O₅Si₂
Molecular Weight:452.739
Hs Code.:

4-[(4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4,5-dihydro-furan-2-yl]-4-hydroxy-cyclohexa-2,5-dienone

Synonyms:

Suppliers and Price of 4-[(4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4,5-dihydro-furan-2-yl]-4-hydroxy-cyclohexa-2,5-dienone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-[(4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4,5-dihydro-furan-2-yl]-4-hydroxy-cyclohexa-2,5-dienone

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-[(4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4,5-dihydro-furan-2-yl]-4-hydroxy-cyclohexa-2,5-dienone

There total 3 articles about 4-[(4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4,5-dihydro-furan-2-yl]-4-hydroxy-cyclohexa-2,5-dienone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 174865-50-0
1-[(4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4,5-dihydro-furan-2-yl]-4,4-dimethoxy-cyclohexa-2,5-dienol

: 174865-51-1
4-[(4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4,5-dihydro-furan-2-yl]-4-hydroxy-cyclohexa-2,5-dienone

Guidance literature:: With sodium dithionite; In tetrahydrofuran; water; for 8.5h; Yield given; Ambient temperature;
DOI:10.1021/jo951344o

Reference yield:

: 173327-56-5
3,5-bis-O,O-(tert-butyldimethylsilyl)-1,2-didehydro-1,2-dideoxy-D-ribofuranose

: 174865-51-1
4-[(4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4,5-dihydro-furan-2-yl]-4-hydroxy-cyclohexa-2,5-dienone

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) t-BuLi / 1.) THF, pentane, -78 deg C, 30 min, 2.) THF, -78 deg C, 5 h 45 min

2: Na₂S₂O₄ / tetrahydrofuran; H₂O / 8.5 h / Ambient temperature

With sodium dithionite; tert.-butyl lithium; In tetrahydrofuran; water;
DOI:10.1021/jo951344o

Reference yield:

: 173327-56-5
3,5-bis-O,O-(tert-butyldimethylsilyl)-1,2-didehydro-1,2-dideoxy-D-ribofuranose

: 106-51-4
p-benzoquinone

: 174865-51-1
4-[(4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4,5-dihydro-furan-2-yl]-4-hydroxy-cyclohexa-2,5-dienone

Guidance literature:: With tert.-butyl lithium; Yield given. Multistep reaction; 1.) THF, pentane, -78 deg C, 1 h, 2.) THF, -78 deg C, 4 h;
DOI:10.1021/jo951344o