trans-[Pd(CH₂C(O)Me)Cl(2,6-xylyl isocyanide)2]

Base Information

Chemical Name:trans-[Pd(CH₂C(O)Me)Cl(2,6-xylyl isocyanide)2]
CAS No.:852993-31-8
Molecular Formula:C₂₁H₂₃ClN₂OPd
Molecular Weight:461.299
Hs Code.:

trans-[Pd(CH<sub>2</sub>C(O)Me)Cl(2,6-xylyl isocyanide)2]

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Chemical Property of trans-[Pd(CH₂C(O)Me)Cl(2,6-xylyl isocyanide)2]

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Technology Process of trans-[Pd(CH₂C(O)Me)Cl(2,6-xylyl isocyanide)2]

There total 2 articles about trans-[Pd(CH₂C(O)Me)Cl(2,6-xylyl isocyanide)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: [Pd(acetonyl)Cl]

: 119072-54-7,2769-71-3
2,6-dimethylphenyl isonitrile

: 852993-31-8
trans-[Pd(CH₂C(O)Me)Cl(2,6-xylyl isocyanide)2]

Guidance literature:: In dichloromethane; Me2C6H3NC (2 equiv.) added to cooled suspn. (-78°C) of Pd complexin CH2Cl2; stirred until solid dissolved; filtered through Celite to cooled flask; filtrate concd. at 0°C; n-pentane added; solid stirred at -40°C for 20 min; filtered; solid washed with n-pentane; air dried; elem. anal.;
DOI:10.1021/om048999c

Reference yield:

: [Pd(acetonyl)Cl]

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 852993-31-8
trans-[Pd(CH₂C(O)Me)Cl(2,6-xylyl isocyanide)2]

: 852993-33-0
[Pd(κ2-C,O-C(NHC6H3-2,6-Me2)CHC(O)Me)Cl(2,6-xyly isocyanide)]

Guidance literature:: In dichloromethane; Me2C6H3NC (2 equiv.) added to suspn. of Pd complex in CH2Cl2; stirred atroom temp.; mixt. of two Pd complexes obtained;
DOI:10.1021/om048999c

Reference yield: 81.0%

: 852993-31-8
trans-[Pd(CH₂C(O)Me)Cl(2,6-xylyl isocyanide)2]

: 852993-33-0
[Pd(κ2-C,O-C(NHC6H3-2,6-Me2)CHC(O)Me)Cl(2,6-xyly isocyanide)]

Guidance literature:: In chloroform; soln. of Pd complex in CHCl3 heated at 40°C for 5 h; filtered through Celite; filtrate concd.; Et2O added slowly; suspn. filtered off; washed with Et2O; air dried; elem. anal.;
DOI:10.1021/om048999c