4,4'-bis(2,2':6',2''-terpyridinyl)triphenylamine

Base Information

Chemical Name:4,4'-bis(2,2':6',2''-terpyridinyl)triphenylamine
CAS No.:909697-66-1
Molecular Formula:C₄₈H₃₃N₇
Molecular Weight:707.837
Hs Code.:

Synonyms:

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Chemical Property of 4,4'-bis(2,2':6',2''-terpyridinyl)triphenylamine

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Technology Process of 4,4'-bis(2,2':6',2''-terpyridinyl)triphenylamine

There total 2 articles about 4,4'-bis(2,2':6',2''-terpyridinyl)triphenylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

: 1122-62-9
2-acetylpyridine

: 53566-95-3
4,4'-diformyltriphenylamine

: 909697-66-1
4,4'-bis(2,2':6',2''-terpyridinyl)triphenylamine

Guidance literature:: 2-acetylpyridine; 4,4'-diformyltriphenylamine; With sodium hydroxide; In ethanol; at 25 ℃; for 24h;

With ammonium acetate; In acetic acid; for 12h; Heating;
DOI:10.1039/b603691k

Reference yield:

: 603-34-9
N,N-diphenylaminobenzene

: 909697-66-1
4,4'-bis(2,2':6',2''-terpyridinyl)triphenylamine

Guidance literature:: Multi-step reaction with 2 steps

1.1: 52 percent / POCl₃ / 1,2-dichloro-ethane / 48 h / 80 °C

2.1: NaOH / ethanol / 24 h / 25 °C

2.2: 34 percent / NH₄OAc / acetic acid / 12 h / Heating

With sodium hydroxide; trichlorophosphate; In ethanol; 1,2-dichloro-ethane;
DOI:10.1039/b603691k

Reference yield: 55.0%

: 909697-66-1
4,4'-bis(2,2':6',2''-terpyridinyl)triphenylamine

: 27860-83-9
Zn⁽²⁺⁾*2BF₄^(1-)*8H₂O=Zn(BF₄)2*8H₂O

: [Zn₆(4,4'-bis(2,2:6',2''-terpyridinyl)triphenylamine)6(BF₄)12]

Guidance literature:: In acetonitrile; addn. of Zn(BF4)2*8H2O to a soln. of ligand in CH3CN, reflux for 48 h; filtration through Celite, addn. of ether, filtration of ppt.;
DOI:10.1039/b603691k